1-(2-Naphth-yl)-3-phenyl-3-(4,5,6,7-tetrahydro-1,2,3-benzoselenadiazol-4- yl)propan-1-one

  • J. Muthukumaran
  • , M. Nachiappan
  • , S. Chitra
  • , P. Manisankar
  • , Suman Bhattacharya
  • , S. Muthusubramanian
  • , R. Krishna
  • , J. Jeyakanthan

Research output: Contribution to journalArticlepeer-review

Abstract

In the title compound, C 25H 22N 2OSe, the fused six-membered cyclo-hexene ring of the 4,5,6,7-tetrahydro-1,2,3- benzoselenadiazole group adopts a near half-chair conformation and the five-membered 1,2,3-selenadiazole ring is essentially planar (r.m.s. deviation = 0.004 Å). There are weak inter-molecular C - H⋯O and C - H⋯π interactions in the crystal structure. Inter-molecular π-π stacking is also observed between the naphthyl units, with a centroid-centroid distance of 3.529 (15) Å.

Original languageEnglish
Pages (from-to)o2010-o2011
JournalActa Crystallographica Section E: Structure Reports Online
Volume67
Issue number8
DOIs
Publication statusPublished - Aug 2011
Externally publishedYes

Keywords

  • data-to-parameter ratio = 13.7
  • mean σ(CC) = 0.004 Å
  • R factor = 0.038
  • single-crystal X-ray study
  • T = 293 K
  • wR factor = 0.096

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