1-D coordination polymers containing benzenedicarboxylate

Susan A. Bourne; Arunendu Mondal; Michael J. Zaworotko

doi:10.1016/S1463-0184(01)00007-7

1-D coordination polymers containing benzenedicarboxylate

Susan A. Bourne, Arunendu Mondal, Michael J. Zaworotko

Research output: Contribution to journal › Article › peer-review

Abstract

The preparation and crystal structures of [Cu(1,3-bdc)(py)₃].11/2 H₂O (1), [Cu(1,3-bdc)(py)₃].H₂O.CH₃OH (2), [Co(1,3-bdc)(py)₃(H₂O)] (3), [Co(1,3-bdc)(py)₃(CH₃OH)].H₂O (4), [Cu(1,3-bdc)(py)₂] (5), [Co(1,3-bdc)(CH₃OH)₄] (6) and [Ni(1,3-bdc)(CH₃OH)₄] (7) are described (1,3-bdc=1,3-benzenedicarboxylic acid; py=pyridine). 1-4 form straight-chain 1-D coordination polymers with interdigitated pyridyl ligands that are engaged in C-H···π hydrogen bonds. 6 and 7 form similar 1-D polymeric chains, but the smaller methanol ligands allow the bdc groups to stack to form π···π interactions. 5 forms a rectangular 2-D grid structure with insufficient space for guest inclusion.

Original language	English
Pages (from-to)	25-36
Number of pages	12
Journal	Crystal Engineering
Volume	4
Issue number	1
DOIs	https://doi.org/10.1016/S1463-0184(01)00007-7
Publication status	Published - Mar 2001
Externally published	Yes

Keywords

Coordination polymers
Crystal structure
Inorganic compounds

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10.1016/S1463-0184(01)00007-7

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@article{217bb52e902c42d48ef4ef5a16a0b301,

title = "1-D coordination polymers containing benzenedicarboxylate",

abstract = "The preparation and crystal structures of [Cu(1,3-bdc)(py)3].11/2 H2O (1), [Cu(1,3-bdc)(py)3].H2O.CH3OH (2), [Co(1,3-bdc)(py)3(H2O)] (3), [Co(1,3-bdc)(py)3(CH3OH)].H2O (4), [Cu(1,3-bdc)(py)2] (5), [Co(1,3-bdc)(CH3OH)4] (6) and [Ni(1,3-bdc)(CH3OH)4] (7) are described (1,3-bdc=1,3-benzenedicarboxylic acid; py=pyridine). 1-4 form straight-chain 1-D coordination polymers with interdigitated pyridyl ligands that are engaged in C-H···π hydrogen bonds. 6 and 7 form similar 1-D polymeric chains, but the smaller methanol ligands allow the bdc groups to stack to form π···π interactions. 5 forms a rectangular 2-D grid structure with insufficient space for guest inclusion.",

keywords = "Coordination polymers, Crystal structure, Inorganic compounds",

author = "Bourne, {Susan A.} and Arunendu Mondal and Zaworotko, {Michael J.}",

year = "2001",

month = mar,

doi = "10.1016/S1463-0184(01)00007-7",

language = "English",

volume = "4",

pages = "25--36",

journal = "Crystal Engineering",

issn = "1463-0184",

number = "1",

}

TY - JOUR

T1 - 1-D coordination polymers containing benzenedicarboxylate

AU - Bourne, Susan A.

AU - Mondal, Arunendu

AU - Zaworotko, Michael J.

PY - 2001/3

Y1 - 2001/3

N2 - The preparation and crystal structures of [Cu(1,3-bdc)(py)3].11/2 H2O (1), [Cu(1,3-bdc)(py)3].H2O.CH3OH (2), [Co(1,3-bdc)(py)3(H2O)] (3), [Co(1,3-bdc)(py)3(CH3OH)].H2O (4), [Cu(1,3-bdc)(py)2] (5), [Co(1,3-bdc)(CH3OH)4] (6) and [Ni(1,3-bdc)(CH3OH)4] (7) are described (1,3-bdc=1,3-benzenedicarboxylic acid; py=pyridine). 1-4 form straight-chain 1-D coordination polymers with interdigitated pyridyl ligands that are engaged in C-H···π hydrogen bonds. 6 and 7 form similar 1-D polymeric chains, but the smaller methanol ligands allow the bdc groups to stack to form π···π interactions. 5 forms a rectangular 2-D grid structure with insufficient space for guest inclusion.

AB - The preparation and crystal structures of [Cu(1,3-bdc)(py)3].11/2 H2O (1), [Cu(1,3-bdc)(py)3].H2O.CH3OH (2), [Co(1,3-bdc)(py)3(H2O)] (3), [Co(1,3-bdc)(py)3(CH3OH)].H2O (4), [Cu(1,3-bdc)(py)2] (5), [Co(1,3-bdc)(CH3OH)4] (6) and [Ni(1,3-bdc)(CH3OH)4] (7) are described (1,3-bdc=1,3-benzenedicarboxylic acid; py=pyridine). 1-4 form straight-chain 1-D coordination polymers with interdigitated pyridyl ligands that are engaged in C-H···π hydrogen bonds. 6 and 7 form similar 1-D polymeric chains, but the smaller methanol ligands allow the bdc groups to stack to form π···π interactions. 5 forms a rectangular 2-D grid structure with insufficient space for guest inclusion.

KW - Coordination polymers

KW - Crystal structure

KW - Inorganic compounds

UR - http://www.scopus.com/inward/record.url?scp=0035269985&partnerID=8YFLogxK

U2 - 10.1016/S1463-0184(01)00007-7

DO - 10.1016/S1463-0184(01)00007-7

M3 - Article

AN - SCOPUS:0035269985

SN - 1463-0184

VL - 4

SP - 25

EP - 36

JO - Crystal Engineering

JF - Crystal Engineering

IS - 1

ER -

1-D coordination polymers containing benzenedicarboxylate

Abstract

Keywords

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