3,7-Diacetyl-1,3,7-triaza-5-phosphabicyclo[3.3.1]nonane (DAPTA) and derivatives: Coordination chemistry and applications

Abdallah G. Mahmoud; M. Fátima C. Guedes da Silva; Armando J.L. Pombeiro

doi:10.1016/j.ccr.2020.213614

3,7-Diacetyl-1,3,7-triaza-5-phosphabicyclo[3.3.1]nonane (DAPTA) and derivatives: Coordination chemistry and applications

Abdallah G. Mahmoud
, M. Fátima C. Guedes da Silva
, Armando J.L. Pombeiro

University of Lisbon

Research output: Contribution to journal › Review article › peer-review

Abstract

The small air-stable hydrophilic aminophosphine 3,7-diacetyl-1,3,7-triaza-5-phosphabicyclo[3.3.1]nonane (DAPTA) has received a remarkable interest during the last two decades due to its aptitude to form metal complexes in water. Water-solubility of transition metal complexes based on DAPTA allowed their application as catalysts in homogeneous aqueous phase or biphasic systems, as anticancer agents in medicinal inorganic chemistry and as photoluminescent materials. This paper reviews the synthetic methods and physical and structural features of DAPTA and related ligands, their metal complexes and subsequent catalytic, medicinal and photoluminescence applications. The SCXRD structures of the compounds are included and referenced with the respective CSD codes for ease of assessment.

Original language	English
Article number	213614
Journal	Coordination Chemistry Reviews
Volume	429
DOIs	https://doi.org/10.1016/j.ccr.2020.213614
Publication status	Published - 15 Feb 2021
Externally published	Yes

Keywords

3,7-Diacetyl-1,3,7-triaza-5-phosphabicyclo[3.3.1]nonane
Catalysis
Coordination chemistry
Medicinal inorganic chemistry
Photoluminescence
Water soluble ligands

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

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10.1016/j.ccr.2020.213614

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title = "3,7-Diacetyl-1,3,7-triaza-5-phosphabicyclo[3.3.1]nonane (DAPTA) and derivatives: Coordination chemistry and applications",

abstract = "The small air-stable hydrophilic aminophosphine 3,7-diacetyl-1,3,7-triaza-5-phosphabicyclo[3.3.1]nonane (DAPTA) has received a remarkable interest during the last two decades due to its aptitude to form metal complexes in water. Water-solubility of transition metal complexes based on DAPTA allowed their application as catalysts in homogeneous aqueous phase or biphasic systems, as anticancer agents in medicinal inorganic chemistry and as photoluminescent materials. This paper reviews the synthetic methods and physical and structural features of DAPTA and related ligands, their metal complexes and subsequent catalytic, medicinal and photoluminescence applications. The SCXRD structures of the compounds are included and referenced with the respective CSD codes for ease of assessment.",

keywords = "3,7-Diacetyl-1,3,7-triaza-5-phosphabicyclo[3.3.1]nonane, Catalysis, Coordination chemistry, Medicinal inorganic chemistry, Photoluminescence, Water soluble ligands",

author = "Mahmoud, \{Abdallah G.\} and \{Guedes da Silva\}, \{M. F{\'a}tima C.\} and Pombeiro, \{Armando J.L.\}",

note = "Publisher Copyright: {\textcopyright} 2020 Elsevier B.V.",

year = "2021",

month = feb,

day = "15",

doi = "10.1016/j.ccr.2020.213614",

language = "English",

volume = "429",

journal = "Coordination Chemistry Reviews",

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TY - JOUR

T1 - 3,7-Diacetyl-1,3,7-triaza-5-phosphabicyclo[3.3.1]nonane (DAPTA) and derivatives

T2 - Coordination chemistry and applications

AU - Mahmoud, Abdallah G.

AU - Guedes da Silva, M. Fátima C.

AU - Pombeiro, Armando J.L.

PY - 2021/2/15

Y1 - 2021/2/15

N2 - The small air-stable hydrophilic aminophosphine 3,7-diacetyl-1,3,7-triaza-5-phosphabicyclo[3.3.1]nonane (DAPTA) has received a remarkable interest during the last two decades due to its aptitude to form metal complexes in water. Water-solubility of transition metal complexes based on DAPTA allowed their application as catalysts in homogeneous aqueous phase or biphasic systems, as anticancer agents in medicinal inorganic chemistry and as photoluminescent materials. This paper reviews the synthetic methods and physical and structural features of DAPTA and related ligands, their metal complexes and subsequent catalytic, medicinal and photoluminescence applications. The SCXRD structures of the compounds are included and referenced with the respective CSD codes for ease of assessment.

AB - The small air-stable hydrophilic aminophosphine 3,7-diacetyl-1,3,7-triaza-5-phosphabicyclo[3.3.1]nonane (DAPTA) has received a remarkable interest during the last two decades due to its aptitude to form metal complexes in water. Water-solubility of transition metal complexes based on DAPTA allowed their application as catalysts in homogeneous aqueous phase or biphasic systems, as anticancer agents in medicinal inorganic chemistry and as photoluminescent materials. This paper reviews the synthetic methods and physical and structural features of DAPTA and related ligands, their metal complexes and subsequent catalytic, medicinal and photoluminescence applications. The SCXRD structures of the compounds are included and referenced with the respective CSD codes for ease of assessment.

KW - 3,7-Diacetyl-1,3,7-triaza-5-phosphabicyclo[3.3.1]nonane

KW - Catalysis

KW - Coordination chemistry

KW - Medicinal inorganic chemistry

KW - Photoluminescence

KW - Water soluble ligands

UR - https://www.scopus.com/pages/publications/85095840837

U2 - 10.1016/j.ccr.2020.213614

DO - 10.1016/j.ccr.2020.213614

M3 - Review article

AN - SCOPUS:85095840837

SN - 0010-8545

VL - 429

JO - Coordination Chemistry Reviews

JF - Coordination Chemistry Reviews

M1 - 213614

ER -

3,7-Diacetyl-1,3,7-triaza-5-phosphabicyclo[3.3.1]nonane (DAPTA) and derivatives: Coordination chemistry and applications

Abstract

Keywords

UN SDGs

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