4-Methoxypyridine-(pyridine-2,6-dicarboxylato-N,O,O′) copper(II)

John J. Perry; Gregory J. McManus; Michael J. Zaworotko

doi:10.1007/s10870-004-7722-4

4-Methoxypyridine-(pyridine-2,6-dicarboxylato-N,O,O′) copper(II)

John J. Perry, Gregory J. McManus, Michael J. Zaworotko

University of South Florida

Research output: Contribution to journal › Article › peer-review

Abstract

The synthesis and X-ray crystal structure of [Cu(C₇H ₃NO₄)(C₆H₇NO)], [Cu(dipic)(4-MeO-Py) ], (dipic = pyridine-2,6-dicarboxylate, 4-MeO-Py = 4-methoxypyridine), is described. Molecules of [Cu(dipic)(4-MeO-Py)] are formed via coordination of the copper(II) cation to two nitrogen atoms, from the dipic and 4-MeO-Py ligands respectively, and to two oxygen atoms from the carboxylate groups of the dipic ligand. The molecules pack in a non-centrosymmetric manner, stacked eclipsed with respect to one another along the b-axis and aligned parallel in a head-to-tail motif. The title compound crystallizes in the orthorhombic space group, Pca2(1), with a = 27.339(3) Å, b = 3.7130(4) Å, c = 11.6859(12) Å, V = 1186.2(2) Å³, and Z = 4. The structure was solved by direct methods and refined by least-squares methods to a final R-factor of 0.0327 for 2648 independent reflections.

Original language	English
Pages (from-to)	877-881
Number of pages	5
Journal	Journal of Chemical Crystallography
Volume	34
Issue number	12
DOIs	https://doi.org/10.1007/s10870-004-7722-4
Publication status	Published - Dec 2004
Externally published	Yes

Keywords

[Cu(dipic)(4-MeO-Py)]
CH⋯O hydrogen bonds
Copper(II)
Crystal structure
NLO
Pyridine-2,6-dicarboxylic acid

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10.1007/s10870-004-7722-4

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@article{2fbd285b4b664adeaf25ac86a9550bcd,

title = "4-Methoxypyridine-(pyridine-2,6-dicarboxylato-N,O,O′) copper(II)",

abstract = "The synthesis and X-ray crystal structure of [Cu(C7H 3NO4)(C6H7NO)], [Cu(dipic)(4-MeO-Py) ], (dipic = pyridine-2,6-dicarboxylate, 4-MeO-Py = 4-methoxypyridine), is described. Molecules of [Cu(dipic)(4-MeO-Py)] are formed via coordination of the copper(II) cation to two nitrogen atoms, from the dipic and 4-MeO-Py ligands respectively, and to two oxygen atoms from the carboxylate groups of the dipic ligand. The molecules pack in a non-centrosymmetric manner, stacked eclipsed with respect to one another along the b-axis and aligned parallel in a head-to-tail motif. The title compound crystallizes in the orthorhombic space group, Pca2(1), with a = 27.339(3) {\AA}, b = 3.7130(4) {\AA}, c = 11.6859(12) {\AA}, V = 1186.2(2) {\AA}3, and Z = 4. The structure was solved by direct methods and refined by least-squares methods to a final R-factor of 0.0327 for 2648 independent reflections.",

keywords = "[Cu(dipic)(4-MeO-Py)], CH⋯O hydrogen bonds, Copper(II), Crystal structure, NLO, Pyridine-2,6-dicarboxylic acid",

author = "Perry, {John J.} and McManus, {Gregory J.} and Zaworotko, {Michael J.}",

year = "2004",

month = dec,

doi = "10.1007/s10870-004-7722-4",

language = "English",

volume = "34",

pages = "877--881",

journal = "Journal of Chemical Crystallography",

issn = "1074-1542",

number = "12",

}

TY - JOUR

T1 - 4-Methoxypyridine-(pyridine-2,6-dicarboxylato-N,O,O′) copper(II)

AU - Perry, John J.

AU - McManus, Gregory J.

AU - Zaworotko, Michael J.

PY - 2004/12

Y1 - 2004/12

N2 - The synthesis and X-ray crystal structure of [Cu(C7H 3NO4)(C6H7NO)], [Cu(dipic)(4-MeO-Py) ], (dipic = pyridine-2,6-dicarboxylate, 4-MeO-Py = 4-methoxypyridine), is described. Molecules of [Cu(dipic)(4-MeO-Py)] are formed via coordination of the copper(II) cation to two nitrogen atoms, from the dipic and 4-MeO-Py ligands respectively, and to two oxygen atoms from the carboxylate groups of the dipic ligand. The molecules pack in a non-centrosymmetric manner, stacked eclipsed with respect to one another along the b-axis and aligned parallel in a head-to-tail motif. The title compound crystallizes in the orthorhombic space group, Pca2(1), with a = 27.339(3) Å, b = 3.7130(4) Å, c = 11.6859(12) Å, V = 1186.2(2) Å3, and Z = 4. The structure was solved by direct methods and refined by least-squares methods to a final R-factor of 0.0327 for 2648 independent reflections.

AB - The synthesis and X-ray crystal structure of [Cu(C7H 3NO4)(C6H7NO)], [Cu(dipic)(4-MeO-Py) ], (dipic = pyridine-2,6-dicarboxylate, 4-MeO-Py = 4-methoxypyridine), is described. Molecules of [Cu(dipic)(4-MeO-Py)] are formed via coordination of the copper(II) cation to two nitrogen atoms, from the dipic and 4-MeO-Py ligands respectively, and to two oxygen atoms from the carboxylate groups of the dipic ligand. The molecules pack in a non-centrosymmetric manner, stacked eclipsed with respect to one another along the b-axis and aligned parallel in a head-to-tail motif. The title compound crystallizes in the orthorhombic space group, Pca2(1), with a = 27.339(3) Å, b = 3.7130(4) Å, c = 11.6859(12) Å, V = 1186.2(2) Å3, and Z = 4. The structure was solved by direct methods and refined by least-squares methods to a final R-factor of 0.0327 for 2648 independent reflections.

KW - [Cu(dipic)(4-MeO-Py)]

KW - CH⋯O hydrogen bonds

KW - Copper(II)

KW - Crystal structure

KW - NLO

KW - Pyridine-2,6-dicarboxylic acid

UR - http://www.scopus.com/inward/record.url?scp=12944320335&partnerID=8YFLogxK

U2 - 10.1007/s10870-004-7722-4

DO - 10.1007/s10870-004-7722-4

M3 - Article

AN - SCOPUS:12944320335

SN - 1074-1542

VL - 34

SP - 877

EP - 881

JO - Journal of Chemical Crystallography

JF - Journal of Chemical Crystallography

IS - 12

ER -

4-Methoxypyridine-(pyridine-2,6-dicarboxylato-N,O,O′) copper(II)

Abstract

Keywords

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