A mixed molecular salt of lithium and sodium breaks the Hume-Rothery rules for solid solutions

Monica Lestari; Matteo Lusi

doi:10.1039/c8cc09850f

A mixed molecular salt of lithium and sodium breaks the Hume-Rothery rules for solid solutions

Monica Lestari, Matteo Lusi

University of Limerick

Research output: Contribution to journal › Article › peer-review

Abstract

The first molecular solid solution of lithium and sodium ions is reported. In spite of the different chemical and structural properties of the parent compounds, the two cations form a homogeneous mixed phase with the isoorotate ion. Such observation appears in contrast with the Hume-Rothery principles for solid solutions. Furthermore the mixed salts in the series are thermally stable up to 100 °C and non-hygroscopic, which makes them relevant for their potential use as a lithium drug substance.

Original language	English
Pages (from-to)	2297-2300
Number of pages	4
Journal	Chemical Communications
Volume	55
Issue number	16
DOIs	https://doi.org/10.1039/c8cc09850f
Publication status	Published - 2019

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title = "A mixed molecular salt of lithium and sodium breaks the Hume-Rothery rules for solid solutions",

abstract = "The first molecular solid solution of lithium and sodium ions is reported. In spite of the different chemical and structural properties of the parent compounds, the two cations form a homogeneous mixed phase with the isoorotate ion. Such observation appears in contrast with the Hume-Rothery principles for solid solutions. Furthermore the mixed salts in the series are thermally stable up to 100 °C and non-hygroscopic, which makes them relevant for their potential use as a lithium drug substance.",

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AU - Lusi, Matteo

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AB - The first molecular solid solution of lithium and sodium ions is reported. In spite of the different chemical and structural properties of the parent compounds, the two cations form a homogeneous mixed phase with the isoorotate ion. Such observation appears in contrast with the Hume-Rothery principles for solid solutions. Furthermore the mixed salts in the series are thermally stable up to 100 °C and non-hygroscopic, which makes them relevant for their potential use as a lithium drug substance.

UR - https://www.scopus.com/pages/publications/85061850331

U2 - 10.1039/c8cc09850f

DO - 10.1039/c8cc09850f

M3 - Article

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AN - SCOPUS:85061850331

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VL - 55

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JO - Chemical Communications

JF - Chemical Communications

IS - 16

ER -

A mixed molecular salt of lithium and sodium breaks the Hume-Rothery rules for solid solutions

Abstract

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