Abstract
The tetradentate ligand phaap combines a bridging alkoxide oxygen and diazine and pyridine nitrogen donors, with five critically positioned binding sites, and on reaction with Mn(ClO4)2·6H2O undergoes a controlled self assembly to produce a unique trigonal bipyramidal oxygen bridged metal cluster with an exact match between the coordination requirements of the five six-coordinate metals and the donor arrangements of the six coordinated ligands.
Original language | English |
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Pages (from-to) | 347-348 |
Number of pages | 2 |
Journal | Chemical Communications |
Issue number | 4 |
DOIs | |
Publication status | Published - 21 Feb 1999 |
Externally published | Yes |