A novel pentamanganese(II) cluster produced by a controlled self assembly process; an exact match between the coordination algorithm of the metals and the ligand binding site arrangement

Craig J. Matthews; Zhiqiang Xu; Sanat K. Mandal; Laurence K. Thompson; Kumar Biradha; Karen Poirier; Michael J. Zaworotko

doi:10.1039/a808970a

A novel pentamanganese(II) cluster produced by a controlled self assembly process; an exact match between the coordination algorithm of the metals and the ligand binding site arrangement

Craig J. Matthews
, Zhiqiang Xu
, Sanat K. Mandal
, Laurence K. Thompson
, Kumar Biradha
, Karen Poirier
, Michael J. Zaworotko

Memorial University of Newfoundland
Saint Mary's University Halifax
University of Winnipeg

Research output: Contribution to journal › Article › peer-review

Abstract

The tetradentate ligand phaap combines a bridging alkoxide oxygen and diazine and pyridine nitrogen donors, with five critically positioned binding sites, and on reaction with Mn(ClO₄)₂·6H₂O undergoes a controlled self assembly to produce a unique trigonal bipyramidal oxygen bridged metal cluster with an exact match between the coordination requirements of the five six-coordinate metals and the donor arrangements of the six coordinated ligands.

Original language	English
Pages (from-to)	347-348
Number of pages	2
Journal	Chemical Communications
Issue number	4
DOIs	https://doi.org/10.1039/a808970a
Publication status	Published - 21 Feb 1999
Externally published	Yes

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10.1039/a808970a

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title = "A novel pentamanganese(II) cluster produced by a controlled self assembly process; an exact match between the coordination algorithm of the metals and the ligand binding site arrangement",

abstract = "The tetradentate ligand phaap combines a bridging alkoxide oxygen and diazine and pyridine nitrogen donors, with five critically positioned binding sites, and on reaction with Mn(ClO4)2·6H2O undergoes a controlled self assembly to produce a unique trigonal bipyramidal oxygen bridged metal cluster with an exact match between the coordination requirements of the five six-coordinate metals and the donor arrangements of the six coordinated ligands.",

author = "Matthews, \{Craig J.\} and Zhiqiang Xu and Mandal, \{Sanat K.\} and Thompson, \{Laurence K.\} and Kumar Biradha and Karen Poirier and Zaworotko, \{Michael J.\}",

year = "1999",

month = feb,

day = "21",

doi = "10.1039/a808970a",

language = "English",

pages = "347--348",

journal = "Chemical Communications",

issn = "1359-7345",

number = "4",

}

A novel pentamanganese(II) cluster produced by a controlled self assembly process; an exact match between the coordination algorithm of the metals and the ligand binding site arrangement. / Matthews, Craig J.; Xu, Zhiqiang; Mandal, Sanat K. et al.
In: Chemical Communications, No. 4, 21.02.1999, p. 347-348.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - A novel pentamanganese(II) cluster produced by a controlled self assembly process; an exact match between the coordination algorithm of the metals and the ligand binding site arrangement

AU - Matthews, Craig J.

AU - Xu, Zhiqiang

AU - Mandal, Sanat K.

AU - Thompson, Laurence K.

AU - Biradha, Kumar

AU - Poirier, Karen

AU - Zaworotko, Michael J.

PY - 1999/2/21

Y1 - 1999/2/21

N2 - The tetradentate ligand phaap combines a bridging alkoxide oxygen and diazine and pyridine nitrogen donors, with five critically positioned binding sites, and on reaction with Mn(ClO4)2·6H2O undergoes a controlled self assembly to produce a unique trigonal bipyramidal oxygen bridged metal cluster with an exact match between the coordination requirements of the five six-coordinate metals and the donor arrangements of the six coordinated ligands.

AB - The tetradentate ligand phaap combines a bridging alkoxide oxygen and diazine and pyridine nitrogen donors, with five critically positioned binding sites, and on reaction with Mn(ClO4)2·6H2O undergoes a controlled self assembly to produce a unique trigonal bipyramidal oxygen bridged metal cluster with an exact match between the coordination requirements of the five six-coordinate metals and the donor arrangements of the six coordinated ligands.

UR - https://www.scopus.com/pages/publications/0033590694

U2 - 10.1039/a808970a

DO - 10.1039/a808970a

M3 - Article

AN - SCOPUS:0033590694

SN - 1359-7345

SP - 347

EP - 348

JO - Chemical Communications

JF - Chemical Communications

IS - 4

ER -

A novel pentamanganese(II) cluster produced by a controlled self assembly process; an exact match between the coordination algorithm of the metals and the ligand binding site arrangement

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