Abstract
We report MPM-1-TIFSIX, a molecular porous material (MPM) based upon the neutral metal complex [Cu2(adenine)4(TiF6) 2], that self-assembles through a hydrogen-bonding network. This MPM is amenable to room-temperature synthesis and activation. Gas adsorption measurements and ideal adsorbed solution theory selectivity predictions at 298 K revealed enhanced CO2 separation performance relative to a previously known variant as well as the highest CO2 uptake and isosteric heat of adsorption yet reported for an MPM. MPM-1-TIFSIX is thermally stable to 568 K and retains porosity and capacity even after immersion in water for 24 h.
Original language | English |
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Pages (from-to) | 10950-10953 |
Number of pages | 4 |
Journal | Journal of the American Chemical Society |
Volume | 135 |
Issue number | 30 |
DOIs | |
Publication status | Published - 31 Jul 2013 |
Externally published | Yes |