A supramolecular hydrogen-bonded network as a diffusion barrier for metal adatoms

Christophe Silien; Minna T. Räis̈nen; Manfred Buck

doi:10.1002/anie.200806267

A supramolecular hydrogen-bonded network as a diffusion barrier for metal adatoms

Christophe Silien
, Minna T. Räis̈nen
, Manfred Buck

University of St Andrews

Research output: Contribution to journal › Article › peer-review

Abstract

Confined in a molecular corral: A supramolecular network changes the mechanism by which underpotential deposition (UPD) of copper proceeds on a gold electrode modified by a selfassembled monolayer (SAM). Lateral diffusion of Cu adatoms is suppressed between adjacent cells of a network/SAM hybrid structure. Instead, UPD occurs by direct deposition into the SAM filled pores of the network, where the Cu adatoms are confined.

Original language	English
Pages (from-to)	3349-3352
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	48
Issue number	18
DOIs	https://doi.org/10.1002/anie.200806267
Publication status	Published - 20 Apr 2009
Externally published	Yes

Access to Document

10.1002/anie.200806267

Cite this

@article{62ebaae168564ad783d355f3060b80ff,

title = "A supramolecular hydrogen-bonded network as a diffusion barrier for metal adatoms",

abstract = "Confined in a molecular corral: A supramolecular network changes the mechanism by which underpotential deposition (UPD) of copper proceeds on a gold electrode modified by a selfassembled monolayer (SAM). Lateral diffusion of Cu adatoms is suppressed between adjacent cells of a network/SAM hybrid structure. Instead, UPD occurs by direct deposition into the SAM filled pores of the network, where the Cu adatoms are confined.",

author = "Christophe Silien and R{\"a}i{\"s}nen, \{Minna T.\} and Manfred Buck",

year = "2009",

month = apr,

day = "20",

doi = "10.1002/anie.200806267",

language = "English",

volume = "48",

pages = "3349--3352",

journal = "Angewandte Chemie - International Edition",

issn = "1433-7851",

number = "18",

}

TY - JOUR

T1 - A supramolecular hydrogen-bonded network as a diffusion barrier for metal adatoms

AU - Silien, Christophe

AU - Räis̈nen, Minna T.

AU - Buck, Manfred

PY - 2009/4/20

Y1 - 2009/4/20

N2 - Confined in a molecular corral: A supramolecular network changes the mechanism by which underpotential deposition (UPD) of copper proceeds on a gold electrode modified by a selfassembled monolayer (SAM). Lateral diffusion of Cu adatoms is suppressed between adjacent cells of a network/SAM hybrid structure. Instead, UPD occurs by direct deposition into the SAM filled pores of the network, where the Cu adatoms are confined.

AB - Confined in a molecular corral: A supramolecular network changes the mechanism by which underpotential deposition (UPD) of copper proceeds on a gold electrode modified by a selfassembled monolayer (SAM). Lateral diffusion of Cu adatoms is suppressed between adjacent cells of a network/SAM hybrid structure. Instead, UPD occurs by direct deposition into the SAM filled pores of the network, where the Cu adatoms are confined.

UR - https://www.scopus.com/pages/publications/70349900161

U2 - 10.1002/anie.200806267

DO - 10.1002/anie.200806267

M3 - Article

AN - SCOPUS:70349900161

SN - 1433-7851

VL - 48

SP - 3349

EP - 3352

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 18

ER -

A supramolecular hydrogen-bonded network as a diffusion barrier for metal adatoms

Abstract

Access to Document

Other files and links

Fingerprint

Cite this