A supramolecular network as sacrificial mask for the generation of a nanopatterned binary self-assembled monolayer

Christophe Silien; Minna T. Räisänen; Manfred Buck

doi:10.1002/smll.200901909

A supramolecular network as sacrificial mask for the generation of a nanopatterned binary self-assembled monolayer

Christophe Silien
, Minna T. Räisänen
, Manfred Buck

University of St Andrews

Research output: Contribution to journal › Article › peer-review

Abstract

(Figure Presented) A supramolecular hydrogen-bonded network adsorbed on Au(111) can corral thiol self-assembled monolayers (SAMs) inside its pores. Enhancing the thermodynamic stability of these SAM nanoislands by Cu underpotential deposition allows selective replacement of the network by a second thiol species. The resulting binary SAM retains the periodicity and symmetry of the original supramolecular mask.

Original language	English
Pages (from-to)	391-394
Number of pages	4
Journal	Small
Volume	6
Issue number	3
DOIs	https://doi.org/10.1002/smll.200901909
Publication status	Published - 5 Feb 2010

Keywords

Electrochemistry
Self-assembled monolayers
Supramolecular networks
Surface chemistry

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10.1002/smll.200901909

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title = "A supramolecular network as sacrificial mask for the generation of a nanopatterned binary self-assembled monolayer",

abstract = "(Figure Presented) A supramolecular hydrogen-bonded network adsorbed on Au(111) can corral thiol self-assembled monolayers (SAMs) inside its pores. Enhancing the thermodynamic stability of these SAM nanoislands by Cu underpotential deposition allows selective replacement of the network by a second thiol species. The resulting binary SAM retains the periodicity and symmetry of the original supramolecular mask.",

keywords = "Electrochemistry, Self-assembled monolayers, Supramolecular networks, Surface chemistry",

author = "Christophe Silien and R{\"a}is{\"a}nen, \{Minna T.\} and Manfred Buck",

year = "2010",

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doi = "10.1002/smll.200901909",

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AU - Silien, Christophe

AU - Räisänen, Minna T.

AU - Buck, Manfred

PY - 2010/2/5

Y1 - 2010/2/5

N2 - (Figure Presented) A supramolecular hydrogen-bonded network adsorbed on Au(111) can corral thiol self-assembled monolayers (SAMs) inside its pores. Enhancing the thermodynamic stability of these SAM nanoislands by Cu underpotential deposition allows selective replacement of the network by a second thiol species. The resulting binary SAM retains the periodicity and symmetry of the original supramolecular mask.

AB - (Figure Presented) A supramolecular hydrogen-bonded network adsorbed on Au(111) can corral thiol self-assembled monolayers (SAMs) inside its pores. Enhancing the thermodynamic stability of these SAM nanoislands by Cu underpotential deposition allows selective replacement of the network by a second thiol species. The resulting binary SAM retains the periodicity and symmetry of the original supramolecular mask.

KW - Electrochemistry

KW - Self-assembled monolayers

KW - Supramolecular networks

KW - Surface chemistry

UR - https://www.scopus.com/pages/publications/75749151280

U2 - 10.1002/smll.200901909

DO - 10.1002/smll.200901909

M3 - Article

C2 - 20020470

AN - SCOPUS:75749151280

SN - 1613-6810

VL - 6

SP - 391

EP - 394

JO - Small

JF - Small

IS - 3

ER -

A supramolecular network as sacrificial mask for the generation of a nanopatterned binary self-assembled monolayer

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Keywords

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