TY - JOUR
T1 - A two dimensional clathrate hydrate
T2 - Tetraethylammonium terephthalate·6 H2O
AU - Furey, W. Scott
AU - Sharma, C. V.Krishnamohan
AU - Zaworotko, Michael J.
PY - 1996
Y1 - 1996
N2 - The crystal structure of tetraethylammonium terephthalate·6H2O, 1·6H2O, monoclinic, I2/a, a = 14.416(5), b = 12.913(2), c = 17.169(4)Å, β = 103.32(4)°, Vol = 3117.4(14), Z = 8, Dcalc = 1.27, reveals a novel 2D clathrate hydrate anionic sheet that is sustained by a hexameric assembly of water molecules linking terephthalate anions through hydrogen bonds. The anionic layers are intercalated by layers of close packed cations and, via numerous inter layer C-H...O hydrogen bonds, form a stable crystalline architecture with high melting point (m.p. 160°C).
AB - The crystal structure of tetraethylammonium terephthalate·6H2O, 1·6H2O, monoclinic, I2/a, a = 14.416(5), b = 12.913(2), c = 17.169(4)Å, β = 103.32(4)°, Vol = 3117.4(14), Z = 8, Dcalc = 1.27, reveals a novel 2D clathrate hydrate anionic sheet that is sustained by a hexameric assembly of water molecules linking terephthalate anions through hydrogen bonds. The anionic layers are intercalated by layers of close packed cations and, via numerous inter layer C-H...O hydrogen bonds, form a stable crystalline architecture with high melting point (m.p. 160°C).
UR - http://www.scopus.com/inward/record.url?scp=0042224070&partnerID=8YFLogxK
U2 - 10.1080/10610279608233962
DO - 10.1080/10610279608233962
M3 - Article
AN - SCOPUS:0042224070
SN - 1061-0278
VL - 8
SP - 9
EP - 11
JO - Supramolecular Chemistry
JF - Supramolecular Chemistry
IS - 1
ER -