A two dimensional clathrate hydrate: Tetraethylammonium terephthalate·6 H2O

W. Scott Furey; C. V.Krishnamohan Sharma; Michael J. Zaworotko

doi:10.1080/10610279608233962

A two dimensional clathrate hydrate: Tetraethylammonium terephthalate·6 H₂O

W. Scott Furey
, C. V.Krishnamohan Sharma
, Michael J. Zaworotko

Saint Mary's University Halifax

Research output: Contribution to journal › Article › peer-review

Abstract

The crystal structure of tetraethylammonium terephthalate·6H₂O, 1·6H₂O, monoclinic, I2/a, a = 14.416(5), b = 12.913(2), c = 17.169(4)Å, β = 103.32(4)°, Vol = 3117.4(14), Z = 8, D_calc = 1.27, reveals a novel 2D clathrate hydrate anionic sheet that is sustained by a hexameric assembly of water molecules linking terephthalate anions through hydrogen bonds. The anionic layers are intercalated by layers of close packed cations and, via numerous inter layer C-H...O hydrogen bonds, form a stable crystalline architecture with high melting point (m.p. 160°C).

Original language	English
Pages (from-to)	9-11
Number of pages	3
Journal	Supramolecular Chemistry
Volume	8
Issue number	1
DOIs	https://doi.org/10.1080/10610279608233962
Publication status	Published - 1996
Externally published	Yes

Access to Document

10.1080/10610279608233962

Cite this

@article{bc79a696d3c44fb8bd9c10dbba19b5b4,

title = "A two dimensional clathrate hydrate: Tetraethylammonium terephthalate·6 H2O",

abstract = "The crystal structure of tetraethylammonium terephthalate·6H2O, 1·6H2O, monoclinic, I2/a, a = 14.416(5), b = 12.913(2), c = 17.169(4){\AA}, β = 103.32(4)°, Vol = 3117.4(14), Z = 8, Dcalc = 1.27, reveals a novel 2D clathrate hydrate anionic sheet that is sustained by a hexameric assembly of water molecules linking terephthalate anions through hydrogen bonds. The anionic layers are intercalated by layers of close packed cations and, via numerous inter layer C-H...O hydrogen bonds, form a stable crystalline architecture with high melting point (m.p. 160°C).",

author = "Furey, \{W. Scott\} and Sharma, \{C. V.Krishnamohan\} and Zaworotko, \{Michael J.\}",

year = "1996",

doi = "10.1080/10610279608233962",

language = "English",

volume = "8",

pages = "9--11",

journal = "Supramolecular Chemistry",

issn = "1061-0278",

number = "1",

}

TY - JOUR

T1 - A two dimensional clathrate hydrate

T2 - Tetraethylammonium terephthalate·6 H2O

AU - Furey, W. Scott

AU - Sharma, C. V.Krishnamohan

AU - Zaworotko, Michael J.

PY - 1996

Y1 - 1996

N2 - The crystal structure of tetraethylammonium terephthalate·6H2O, 1·6H2O, monoclinic, I2/a, a = 14.416(5), b = 12.913(2), c = 17.169(4)Å, β = 103.32(4)°, Vol = 3117.4(14), Z = 8, Dcalc = 1.27, reveals a novel 2D clathrate hydrate anionic sheet that is sustained by a hexameric assembly of water molecules linking terephthalate anions through hydrogen bonds. The anionic layers are intercalated by layers of close packed cations and, via numerous inter layer C-H...O hydrogen bonds, form a stable crystalline architecture with high melting point (m.p. 160°C).

AB - The crystal structure of tetraethylammonium terephthalate·6H2O, 1·6H2O, monoclinic, I2/a, a = 14.416(5), b = 12.913(2), c = 17.169(4)Å, β = 103.32(4)°, Vol = 3117.4(14), Z = 8, Dcalc = 1.27, reveals a novel 2D clathrate hydrate anionic sheet that is sustained by a hexameric assembly of water molecules linking terephthalate anions through hydrogen bonds. The anionic layers are intercalated by layers of close packed cations and, via numerous inter layer C-H...O hydrogen bonds, form a stable crystalline architecture with high melting point (m.p. 160°C).

UR - https://www.scopus.com/pages/publications/0042224070

U2 - 10.1080/10610279608233962

DO - 10.1080/10610279608233962

M3 - Article

AN - SCOPUS:0042224070

SN - 1061-0278

VL - 8

SP - 9

EP - 11

JO - Supramolecular Chemistry

JF - Supramolecular Chemistry

IS - 1

ER -

A two dimensional clathrate hydrate: Tetraethylammonium terephthalate·6 H₂O

Abstract

Access to Document

Other files and links

Fingerprint

Cite this