A Werner complex that exhibits high selectivity for o -xylene

Adrianna M. Kałuża; Soumya Mukherjee; Shi Qiang Wang; Daniel J. O'Hearn; Michael J. Zaworotko

doi:10.1039/c9cc09525j

A Werner complex that exhibits high selectivity for o -xylene

Adrianna M. Kałuża
, Soumya Mukherjee
, Shi Qiang Wang
, Daniel J. O'Hearn
, Michael J. Zaworotko

University of Limerick

Research output: Contribution to journal › Article › peer-review

Abstract

[Cu(4-phenylpyridine)₄(trifluoromethanesulfonate)₂] is a new Werner complex that exhibits switching behaviour between non-porous (apohost) and porous (guest-loaded) phases upon exposure to o-xylene but not when exposed to other C8 isomers. High o-xylene selectivity (>6) vs. the other C8 isomers was observed from binary mixtures, only the third occurrence across all sorbent types.

Original language	English
Pages (from-to)	1940-1943
Number of pages	4
Journal	Chemical Communications
Volume	56
Issue number	13
DOIs	https://doi.org/10.1039/c9cc09525j
Publication status	Published - 14 Feb 2020

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AU - Kałuża, Adrianna M.

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AU - O'Hearn, Daniel J.

AU - Zaworotko, Michael J.

PY - 2020/2/14

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N2 - [Cu(4-phenylpyridine)4(trifluoromethanesulfonate)2] is a new Werner complex that exhibits switching behaviour between non-porous (apohost) and porous (guest-loaded) phases upon exposure to o-xylene but not when exposed to other C8 isomers. High o-xylene selectivity (>6) vs. the other C8 isomers was observed from binary mixtures, only the third occurrence across all sorbent types.

AB - [Cu(4-phenylpyridine)4(trifluoromethanesulfonate)2] is a new Werner complex that exhibits switching behaviour between non-porous (apohost) and porous (guest-loaded) phases upon exposure to o-xylene but not when exposed to other C8 isomers. High o-xylene selectivity (>6) vs. the other C8 isomers was observed from binary mixtures, only the third occurrence across all sorbent types.

UR - https://www.scopus.com/pages/publications/85079353016

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DO - 10.1039/c9cc09525j

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JO - Chemical Communications

JF - Chemical Communications

IS - 13

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A Werner complex that exhibits high selectivity for o -xylene

Abstract

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