TY - JOUR
T1 - Acetylene storage performance of [Ni(4,4′-bipyridine)2(NCS)2]: N , a switching square lattice coordination network
AU - Wang, Shi Qiang
AU - Darwish, Shaza
AU - Meng, Xiao Qing
AU - Chang, Ze
AU - Bu, Xian He
AU - Zaworotko, Michael J.
N1 - Publisher Copyright:
© The Royal Society of Chemistry.
PY - 2022/2/4
Y1 - 2022/2/4
N2 - We report that the previously reported square lattice coordination network [Ni(4,4′-bipyridine)2(NCS)2]n, sql-1-Ni-NCS, undergoes acetylene induced switching between closed (nonporous) and open (porous) phases. The resulting stepped sorption isotherms exhibit temperature controlled steps, consistent high uptake and benchmark working capacity (185 cm-3 g-1 or 189 cm-3, 1-3.2 bar, 288 K) for acetylene storage.
AB - We report that the previously reported square lattice coordination network [Ni(4,4′-bipyridine)2(NCS)2]n, sql-1-Ni-NCS, undergoes acetylene induced switching between closed (nonporous) and open (porous) phases. The resulting stepped sorption isotherms exhibit temperature controlled steps, consistent high uptake and benchmark working capacity (185 cm-3 g-1 or 189 cm-3, 1-3.2 bar, 288 K) for acetylene storage.
UR - http://www.scopus.com/inward/record.url?scp=85123969036&partnerID=8YFLogxK
U2 - 10.1039/d1cc06638b
DO - 10.1039/d1cc06638b
M3 - Article
C2 - 35005756
AN - SCOPUS:85123969036
SN - 1359-7345
VL - 58
SP - 1534
EP - 1537
JO - Chemical Communications
JF - Chemical Communications
IS - 10
ER -