Acetylene storage performance of [Ni(4,4′-bipyridine)2(NCS)2]: N , a switching square lattice coordination network

Shi Qiang Wang; Shaza Darwish; Xiao Qing Meng; Ze Chang; Xian He Bu; Michael J. Zaworotko

doi:10.1039/d1cc06638b

Acetylene storage performance of [Ni(4,4′-bipyridine)₂(NCS)₂]_{: N}, a switching square lattice coordination network

Shi Qiang Wang
, Shaza Darwish
, Xiao Qing Meng
, Ze Chang
, Xian He Bu
, Michael J. Zaworotko

Research output: Contribution to journal › Article › peer-review

Abstract

We report that the previously reported square lattice coordination network [Ni(4,4′-bipyridine)2(NCS)2]n, sql-1-Ni-NCS, undergoes acetylene induced switching between closed (nonporous) and open (porous) phases. The resulting stepped sorption isotherms exhibit temperature controlled steps, consistent high uptake and benchmark working capacity (185 cm-3 g-1 or 189 cm-3, 1-3.2 bar, 288 K) for acetylene storage.

Original language	English
Pages (from-to)	1534-1537
Number of pages	4
Journal	Chemical Communications
Volume	58
Issue number	10
DOIs	https://doi.org/10.1039/d1cc06638b
Publication status	Published - 4 Feb 2022

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title = "Acetylene storage performance of [Ni(4,4′-bipyridine)2(NCS)2]: N , a switching square lattice coordination network",

abstract = "We report that the previously reported square lattice coordination network [Ni(4,4′-bipyridine)2(NCS)2]n, sql-1-Ni-NCS, undergoes acetylene induced switching between closed (nonporous) and open (porous) phases. The resulting stepped sorption isotherms exhibit temperature controlled steps, consistent high uptake and benchmark working capacity (185 cm-3 g-1 or 189 cm-3, 1-3.2 bar, 288 K) for acetylene storage.",

author = "Wang, \{Shi Qiang\} and Shaza Darwish and Meng, \{Xiao Qing\} and Ze Chang and Bu, \{Xian He\} and Zaworotko, \{Michael J.\}",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry.",

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doi = "10.1039/d1cc06638b",

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T1 - Acetylene storage performance of [Ni(4,4′-bipyridine)2(NCS)2]: N , a switching square lattice coordination network

AU - Wang, Shi Qiang

AU - Darwish, Shaza

AU - Meng, Xiao Qing

AU - Chang, Ze

AU - Bu, Xian He

AU - Zaworotko, Michael J.

N1 - Publisher Copyright: © The Royal Society of Chemistry.

PY - 2022/2/4

Y1 - 2022/2/4

N2 - We report that the previously reported square lattice coordination network [Ni(4,4′-bipyridine)2(NCS)2]n, sql-1-Ni-NCS, undergoes acetylene induced switching between closed (nonporous) and open (porous) phases. The resulting stepped sorption isotherms exhibit temperature controlled steps, consistent high uptake and benchmark working capacity (185 cm-3 g-1 or 189 cm-3, 1-3.2 bar, 288 K) for acetylene storage.

AB - We report that the previously reported square lattice coordination network [Ni(4,4′-bipyridine)2(NCS)2]n, sql-1-Ni-NCS, undergoes acetylene induced switching between closed (nonporous) and open (porous) phases. The resulting stepped sorption isotherms exhibit temperature controlled steps, consistent high uptake and benchmark working capacity (185 cm-3 g-1 or 189 cm-3, 1-3.2 bar, 288 K) for acetylene storage.

UR - https://www.scopus.com/pages/publications/85123969036

U2 - 10.1039/d1cc06638b

DO - 10.1039/d1cc06638b

M3 - Article

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AN - SCOPUS:85123969036

SN - 1359-7345

VL - 58

SP - 1534

EP - 1537

JO - Chemical Communications

JF - Chemical Communications

IS - 10

ER -

Acetylene storage performance of [Ni(4,4′-bipyridine)₂(NCS)₂]_{: N}, a switching square lattice coordination network

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