Adsorbate-dependent phase switching in the square lattice topology coordination network [Ni(4,4′-bipyridine)2(NCS)2]n

Shi Qiang Wang; Shaza Darwish; Michael J. Zaworotko

doi:10.1039/d2cc06549e

Adsorbate-dependent phase switching in the square lattice topology coordination network [Ni(4,4′-bipyridine)₂(NCS)₂]_n

Shi Qiang Wang
, Shaza Darwish
, Michael J. Zaworotko

University of Limerick
Agency for Science, Technology and Research, Singapore

Research output: Contribution to journal › Article › peer-review

Abstract

Switching coordination networks (CNs) featuring stepped sorption isotherms that are accompanied by phase changes offer promise for gas storage and separation applications. However, their responsiveness to different adsorbates remains largely understudied. Herein, we report the variable switching behaviour of a previously known square lattice (sql) topology CN, [Ni(4,4′-bipyridine)₂(NCS)₂] (sql-1-Ni-NCS), with respect to nine gaseous adsorbates.

Original language	English
Pages (from-to)	559-562
Number of pages	4
Journal	Chemical Communications
Volume	59
Issue number	5
DOIs	https://doi.org/10.1039/d2cc06549e
Publication status	Published - 8 Dec 2022

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abstract = "Switching coordination networks (CNs) featuring stepped sorption isotherms that are accompanied by phase changes offer promise for gas storage and separation applications. However, their responsiveness to different adsorbates remains largely understudied. Herein, we report the variable switching behaviour of a previously known square lattice (sql) topology CN, [Ni(4,4′-bipyridine)2(NCS)2] (sql-1-Ni-NCS), with respect to nine gaseous adsorbates.",

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N2 - Switching coordination networks (CNs) featuring stepped sorption isotherms that are accompanied by phase changes offer promise for gas storage and separation applications. However, their responsiveness to different adsorbates remains largely understudied. Herein, we report the variable switching behaviour of a previously known square lattice (sql) topology CN, [Ni(4,4′-bipyridine)2(NCS)2] (sql-1-Ni-NCS), with respect to nine gaseous adsorbates.

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Adsorbate-dependent phase switching in the square lattice topology coordination network [Ni(4,4′-bipyridine)₂(NCS)₂]_n

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