Ammonium-crown ether supramolecular cation-templated assembly of an unprecedented heterobicluster-metal coordination polymer with enhanced NLO properties

Jinfang Zhang, Ding Jia, Mark G. Humphrey, Suci Meng, Michael J. Zaworotko, Marie P. Cifuentes, Chi Zhang

Research output: Contribution to journalArticlepeer-review

Abstract

An ammonium-crown ether host-guest supramolecular cation-templated synthetic methodology has been developed to construct a structurally unprecedented heterobicluster-metal coordination polymer (HCM-CP 1) based on tetranuclear clusters [WS4Cu3]+ with different connection environments, pentanuclear clusters [WS4Cu4]2+, and Cu+ building metal ions. HCM-CP 1 exhibits enhanced NLO properties, which may be ascribed to the incorporation of diverse building cluster components.

Original languageEnglish
Pages (from-to)3797-3800
Number of pages4
JournalChemical Communications
Volume52
Issue number19
DOIs
Publication statusPublished - 2016

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