Abstract
An ammonium-crown ether host-guest supramolecular cation-templated synthetic methodology has been developed to construct a structurally unprecedented heterobicluster-metal coordination polymer (HCM-CP 1) based on tetranuclear clusters [WS4Cu3]+ with different connection environments, pentanuclear clusters [WS4Cu4]2+, and Cu+ building metal ions. HCM-CP 1 exhibits enhanced NLO properties, which may be ascribed to the incorporation of diverse building cluster components.
Original language | English |
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Pages (from-to) | 3797-3800 |
Number of pages | 4 |
Journal | Chemical Communications |
Volume | 52 |
Issue number | 19 |
DOIs | |
Publication status | Published - 2016 |