Ammonium-crown ether supramolecular cation-templated assembly of an unprecedented heterobicluster-metal coordination polymer with enhanced NLO properties

Jinfang Zhang; Ding Jia; Mark G. Humphrey; Suci Meng; Michael J. Zaworotko; Marie P. Cifuentes; Chi Zhang

doi:10.1039/c5cc10076c

Ammonium-crown ether supramolecular cation-templated assembly of an unprecedented heterobicluster-metal coordination polymer with enhanced NLO properties

Jinfang Zhang
, Ding Jia
, Mark G. Humphrey
, Suci Meng
, Michael J. Zaworotko
, Marie P. Cifuentes
, Chi Zhang

Research output: Contribution to journal › Article › peer-review

Abstract

An ammonium-crown ether host-guest supramolecular cation-templated synthetic methodology has been developed to construct a structurally unprecedented heterobicluster-metal coordination polymer (HCM-CP 1) based on tetranuclear clusters [WS₄Cu₃]⁺ with different connection environments, pentanuclear clusters [WS₄Cu₄]²⁺, and Cu⁺ building metal ions. HCM-CP 1 exhibits enhanced NLO properties, which may be ascribed to the incorporation of diverse building cluster components.

Original language	English
Pages (from-to)	3797-3800
Number of pages	4
Journal	Chemical Communications
Volume	52
Issue number	19
DOIs	https://doi.org/10.1039/c5cc10076c
Publication status	Published - 2016

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10.1039/c5cc10076c

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title = "Ammonium-crown ether supramolecular cation-templated assembly of an unprecedented heterobicluster-metal coordination polymer with enhanced NLO properties",

abstract = "An ammonium-crown ether host-guest supramolecular cation-templated synthetic methodology has been developed to construct a structurally unprecedented heterobicluster-metal coordination polymer (HCM-CP 1) based on tetranuclear clusters [WS4Cu3]+ with different connection environments, pentanuclear clusters [WS4Cu4]2+, and Cu+ building metal ions. HCM-CP 1 exhibits enhanced NLO properties, which may be ascribed to the incorporation of diverse building cluster components.",

author = "Jinfang Zhang and Ding Jia and Humphrey, \{Mark G.\} and Suci Meng and Zaworotko, \{Michael J.\} and Cifuentes, \{Marie P.\} and Chi Zhang",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry 2016.",

year = "2016",

doi = "10.1039/c5cc10076c",

language = "English",

volume = "52",

pages = "3797--3800",

journal = "Chemical Communications",

issn = "1359-7345",

number = "19",

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T1 - Ammonium-crown ether supramolecular cation-templated assembly of an unprecedented heterobicluster-metal coordination polymer with enhanced NLO properties

AU - Zhang, Jinfang

AU - Jia, Ding

AU - Humphrey, Mark G.

AU - Meng, Suci

AU - Zaworotko, Michael J.

AU - Cifuentes, Marie P.

AU - Zhang, Chi

N1 - Publisher Copyright: © The Royal Society of Chemistry 2016.

PY - 2016

Y1 - 2016

N2 - An ammonium-crown ether host-guest supramolecular cation-templated synthetic methodology has been developed to construct a structurally unprecedented heterobicluster-metal coordination polymer (HCM-CP 1) based on tetranuclear clusters [WS4Cu3]+ with different connection environments, pentanuclear clusters [WS4Cu4]2+, and Cu+ building metal ions. HCM-CP 1 exhibits enhanced NLO properties, which may be ascribed to the incorporation of diverse building cluster components.

AB - An ammonium-crown ether host-guest supramolecular cation-templated synthetic methodology has been developed to construct a structurally unprecedented heterobicluster-metal coordination polymer (HCM-CP 1) based on tetranuclear clusters [WS4Cu3]+ with different connection environments, pentanuclear clusters [WS4Cu4]2+, and Cu+ building metal ions. HCM-CP 1 exhibits enhanced NLO properties, which may be ascribed to the incorporation of diverse building cluster components.

UR - https://www.scopus.com/pages/publications/84960879318

U2 - 10.1039/c5cc10076c

DO - 10.1039/c5cc10076c

M3 - Article

AN - SCOPUS:84960879318

SN - 1359-7345

VL - 52

SP - 3797

EP - 3800

JO - Chemical Communications

JF - Chemical Communications

IS - 19

ER -

Ammonium-crown ether supramolecular cation-templated assembly of an unprecedented heterobicluster-metal coordination polymer with enhanced NLO properties

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