An asymmetrically connected hexanuclear DyIII6 cluster exhibiting slow magnetic relaxation

Soumya Mukherjee; Abhijeet K. Chaudhari; Shufang Xue; Jinkui Tang; Sujit K. Ghosh

doi:10.1016/j.inoche.2013.06.027

An asymmetrically connected hexanuclear Dy^III₆ cluster exhibiting slow magnetic relaxation

Soumya Mukherjee, Abhijeet K. Chaudhari, Shufang Xue, Jinkui Tang, Sujit K. Ghosh

Research output: Contribution to journal › Article › peer-review

Abstract

A new hexanuclear dysprosium(III) cluster [Dy₆(L) ₇(HL)(MeOH)₂(H₂O)(OH)₂(OAc)] (1) has been synthesized from the schiff base ligand o-phenolsalicylimine and dysprosium nitrate. This unique Dy^III₆ cluster, constituted of an exclusive combination of two vertex-sharing and one edge-sharing high-anisotropy Dy₃ triangles assembled together forming an unprecedentedly asymmetric homometallic Dy^III₆ core, shows slow relaxation of the magnetization.

Original language	English
Pages (from-to)	144-148
Number of pages	5
Journal	Inorganic Chemistry Communications
Volume	35
DOIs	https://doi.org/10.1016/j.inoche.2013.06.027
Publication status	Published - 2013
Externally published	Yes

Keywords

Asymmetry
Cluster compounds
Dysprosium
Slow magnetic relaxation

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10.1016/j.inoche.2013.06.027

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@article{fd8f35722fc74e8798e209a67cd75340,

title = "An asymmetrically connected hexanuclear DyIII6 cluster exhibiting slow magnetic relaxation",

abstract = "A new hexanuclear dysprosium(III) cluster [Dy6(L) 7(HL)(MeOH)2(H2O)(OH)2(OAc)] (1) has been synthesized from the schiff base ligand o-phenolsalicylimine and dysprosium nitrate. This unique DyIII6 cluster, constituted of an exclusive combination of two vertex-sharing and one edge-sharing high-anisotropy Dy3 triangles assembled together forming an unprecedentedly asymmetric homometallic DyIII6 core, shows slow relaxation of the magnetization.",

keywords = "Asymmetry, Cluster compounds, Dysprosium, Slow magnetic relaxation",

author = "Soumya Mukherjee and Chaudhari, \{Abhijeet K.\} and Shufang Xue and Jinkui Tang and Ghosh, \{Sujit K.\}",

year = "2013",

doi = "10.1016/j.inoche.2013.06.027",

language = "English",

volume = "35",

pages = "144--148",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

}

TY - JOUR

T1 - An asymmetrically connected hexanuclear DyIII6 cluster exhibiting slow magnetic relaxation

AU - Mukherjee, Soumya

AU - Chaudhari, Abhijeet K.

AU - Xue, Shufang

AU - Tang, Jinkui

AU - Ghosh, Sujit K.

PY - 2013

Y1 - 2013

N2 - A new hexanuclear dysprosium(III) cluster [Dy6(L) 7(HL)(MeOH)2(H2O)(OH)2(OAc)] (1) has been synthesized from the schiff base ligand o-phenolsalicylimine and dysprosium nitrate. This unique DyIII6 cluster, constituted of an exclusive combination of two vertex-sharing and one edge-sharing high-anisotropy Dy3 triangles assembled together forming an unprecedentedly asymmetric homometallic DyIII6 core, shows slow relaxation of the magnetization.

AB - A new hexanuclear dysprosium(III) cluster [Dy6(L) 7(HL)(MeOH)2(H2O)(OH)2(OAc)] (1) has been synthesized from the schiff base ligand o-phenolsalicylimine and dysprosium nitrate. This unique DyIII6 cluster, constituted of an exclusive combination of two vertex-sharing and one edge-sharing high-anisotropy Dy3 triangles assembled together forming an unprecedentedly asymmetric homometallic DyIII6 core, shows slow relaxation of the magnetization.

KW - Asymmetry

KW - Cluster compounds

KW - Dysprosium

KW - Slow magnetic relaxation

UR - https://www.scopus.com/pages/publications/84879822405

U2 - 10.1016/j.inoche.2013.06.027

DO - 10.1016/j.inoche.2013.06.027

M3 - Article

AN - SCOPUS:84879822405

SN - 1387-7003

VL - 35

SP - 144

EP - 148

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

ER -

An asymmetrically connected hexanuclear Dy^III₆ cluster exhibiting slow magnetic relaxation

Abstract

Keywords

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