An Ideal Molecular Sieve for Acetylene Removal from Ethylene with Record Selectivity and Productivity

Bin Li, Xili Cui, Daniel O'Nolan, Hui Min Wen, Mengdie Jiang, Rajamani Krishna, Hui Wu, Rui Biao Lin, Yu Sheng Chen, Daqiang Yuan, Huabin Xing, Wei Zhou, Qilong Ren, Guodong Qian, Michael J. Zaworotko, Banglin Chen

Research output: Contribution to journalArticlepeer-review

Abstract

Realization of ideal molecular sieves, in which the larger gas molecules are completely blocked without sacrificing high adsorption capacities of the preferred smaller gas molecules, can significantly reduce energy costs for gas separation and purification and thus facilitate a possible technological transformation from the traditional energy-intensive cryogenic distillation to the energy-efficient, adsorbent-based separation and purification in the future. Although extensive research endeavors are pursued to target ideal molecular sieves among diverse porous materials, over the past several decades, ideal molecular sieves for the separation and purification of light hydrocarbons are rarely realized. Herein, an ideal porous material, SIFSIX-14-Cu-i (also termed as UTSA-200), is reported with ultrafine tuning of pore size (3.4 Å) to effectively block ethylene (C2H4) molecules but to take up a record-high amount of acetylene (C2H2, 58 cm3 cm−3 under 0.01 bar and 298 K). The material therefore sets up new benchmarks for both the adsorption capacity and selectivity, and thus provides a record purification capacity for the removal of trace C2H2 from C2H4 with 1.18 mmol g−1 C2H2 uptake capacity from a 1/99 C2H2/C2H4 mixture to produce 99.9999% pure C2H4 (much higher than the acceptable purity of 99.996% for polymer-grade C2H4), as demonstrated by experimental breakthrough curves.

Original languageEnglish
Article number1704210
JournalAdvanced Materials
Volume29
Issue number47
DOIs
Publication statusPublished - 20 Dec 2017

Keywords

  • acetylene
  • ethylene purification
  • gas separation
  • molecular sieves
  • porous materials

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