Binder-free germanium nanoparticle decorated multi-wall carbon nanotube anodes prepared via two-step electrophoretic deposition for high capacity Li-ion batteries

Xuan Manh Pham, Syed Abdul Ahad, Niraj Nitish Patil, Hugh Geaney, Shalini Singh, Kevin M. Ryan

Research output: Contribution to journalArticlepeer-review

Abstract

Germanium (Ge) has a high theoretical specific capacity (1384 mA h g−1) and fast lithium-ion diffusivity, which makes it an attractive anode material for lithium-ion batteries (LIBs). However, large volume changes during lithiation can lead to poor capacity retention and rate capability. Here, electrophoretic deposition (EPD) is used as a facile strategy to prepare Ge nanoparticle carbon-nanotube (Ge/CNT) electrodes. The Ge and CNT mass ratio in the Ge/CNT nanocomposites can be controlled by varying the deposition time, voltage, and concentration of the Ge NP dispersion in the EPD process. The optimized Ge/CNT nanocomposite exhibited long-term cyclic stability, with a capacity of 819 mA h g−1 after 1000 cycles at C/5 and a reversible capacity of 686 mA h g−1 after 350 cycles (with a minuscule capacity loss of 0.07% per cycle) at 1C. The Ge/CNT nanocomposite electrodes delivered dramatically improved cycling stability compared to control Ge nanoparticles. This can be attributed to the synergistic effects of implanting Ge into a 3D interconnected CNT network which acts as a buffer layer to accommodate the volume expansion of Ge NPs during lithiation/delithiation, limiting cracking and/or crumbling, to retain the integrity of the Ge/CNT nanocomposite electrodes.

Original languageEnglish
Pages (from-to)637-645
Number of pages9
JournalNanoscale Horizons
DOIs
Publication statusAccepted/In press - 2024

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