Bottom up synthesis that does not start at the bottom: Quadruple covalent cross-linking of nanoscale faceted polyhedra

John J. Perry IV; Victor Ch Kravtsov; Gregory J. McManus; Michael J. Zaworotko

doi:10.1021/ja0734952

Bottom up synthesis that does not start at the bottom: Quadruple covalent cross-linking of nanoscale faceted polyhedra

John J. Perry IV, Victor Ch Kravtsov, Gregory J. McManus, Michael J. Zaworotko

Research output: Contribution to journal › Article › peer-review

Abstract

A novel 3D metal-organic coordination polymer constructed from hollow, spherical, nanometer-sized molecular faceted polyhedra and a flexible tetracarboxylate ligand designed to simultaneously assemble and cross-link these nanoballs in situ has been synthesized and structurally characterized. The crystal structure involves 2-fold interpenetration with each framework exhibiting pores of dimensions which vary from less than 1 nm to just over 2.5 nm.

Original language	English
Pages (from-to)	10076-10077
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	129
Issue number	33
DOIs	https://doi.org/10.1021/ja0734952
Publication status	Published - 22 Aug 2007
Externally published	Yes

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10.1021/ja0734952

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title = "Bottom up synthesis that does not start at the bottom: Quadruple covalent cross-linking of nanoscale faceted polyhedra",

abstract = "A novel 3D metal-organic coordination polymer constructed from hollow, spherical, nanometer-sized molecular faceted polyhedra and a flexible tetracarboxylate ligand designed to simultaneously assemble and cross-link these nanoballs in situ has been synthesized and structurally characterized. The crystal structure involves 2-fold interpenetration with each framework exhibiting pores of dimensions which vary from less than 1 nm to just over 2.5 nm.",

author = "\{Perry IV\}, \{John J.\} and Kravtsov, \{Victor Ch\} and McManus, \{Gregory J.\} and Zaworotko, \{Michael J.\}",

year = "2007",

month = aug,

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doi = "10.1021/ja0734952",

language = "English",

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pages = "10076--10077",

journal = "Journal of the American Chemical Society",

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AU - Perry IV, John J.

AU - Kravtsov, Victor Ch

AU - McManus, Gregory J.

AU - Zaworotko, Michael J.

PY - 2007/8/22

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N2 - A novel 3D metal-organic coordination polymer constructed from hollow, spherical, nanometer-sized molecular faceted polyhedra and a flexible tetracarboxylate ligand designed to simultaneously assemble and cross-link these nanoballs in situ has been synthesized and structurally characterized. The crystal structure involves 2-fold interpenetration with each framework exhibiting pores of dimensions which vary from less than 1 nm to just over 2.5 nm.

AB - A novel 3D metal-organic coordination polymer constructed from hollow, spherical, nanometer-sized molecular faceted polyhedra and a flexible tetracarboxylate ligand designed to simultaneously assemble and cross-link these nanoballs in situ has been synthesized and structurally characterized. The crystal structure involves 2-fold interpenetration with each framework exhibiting pores of dimensions which vary from less than 1 nm to just over 2.5 nm.

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M3 - Article

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JF - Journal of the American Chemical Society

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Bottom up synthesis that does not start at the bottom: Quadruple covalent cross-linking of nanoscale faceted polyhedra

Abstract

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