TY - JOUR
T1 - Can a liquid drop on a substrate be in equilibrium with saturated vapor?
AU - Benilov, E. S.
N1 - Publisher Copyright:
© 2021 American Physical Society.
PY - 2021/9
Y1 - 2021/9
N2 - It is well known that liquid and saturated vapor, separated by a flat interface in an unbounded space, are in equilibrium. One would similarly expect a liquid drop, sitting on a flat substrate, to be in equilibrium with the vapor surrounding it. Yet, it is not: as shown in this work, the drop evaporates. Mathematically, this conclusion is deduced using the diffuse-interface model, but it is also reformulated in terms of the maximum-entropy principle, suggesting model independence. Physically, evaporation of drops is due to the so-called Kelvin effect, which gives rise to a liquid-to-vapor mass flux if the boundary of the liquid phase is convex.
AB - It is well known that liquid and saturated vapor, separated by a flat interface in an unbounded space, are in equilibrium. One would similarly expect a liquid drop, sitting on a flat substrate, to be in equilibrium with the vapor surrounding it. Yet, it is not: as shown in this work, the drop evaporates. Mathematically, this conclusion is deduced using the diffuse-interface model, but it is also reformulated in terms of the maximum-entropy principle, suggesting model independence. Physically, evaporation of drops is due to the so-called Kelvin effect, which gives rise to a liquid-to-vapor mass flux if the boundary of the liquid phase is convex.
UR - http://www.scopus.com/inward/record.url?scp=85115170156&partnerID=8YFLogxK
U2 - 10.1103/PhysRevE.104.L032103
DO - 10.1103/PhysRevE.104.L032103
M3 - Article
C2 - 34654164
AN - SCOPUS:85115170156
SN - 2470-0045
VL - 104
SP - -
JO - Physical Review E - Statistical Physics, Plasmas, Fluids, and Related Interdisciplinary Topics
JF - Physical Review E - Statistical Physics, Plasmas, Fluids, and Related Interdisciplinary Topics
IS - 3
M1 - L032103
ER -