Abstract
It is well known that liquid and saturated vapor, separated by a flat interface in an unbounded space, are in equilibrium. One would similarly expect a liquid drop, sitting on a flat substrate, to be in equilibrium with the vapor surrounding it. Yet, it is not: as shown in this work, the drop evaporates. Mathematically, this conclusion is deduced using the diffuse-interface model, but it is also reformulated in terms of the maximum-entropy principle, suggesting model independence. Physically, evaporation of drops is due to the so-called Kelvin effect, which gives rise to a liquid-to-vapor mass flux if the boundary of the liquid phase is convex.
| Original language | English |
|---|---|
| Article number | L032103 |
| Journal | Physical Review E - Statistical Physics, Plasmas, Fluids, and Related Interdisciplinary Topics |
| Volume | 104 |
| Issue number | 3 |
| DOIs | |
| Publication status | Published - Sep 2021 |
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