TY - JOUR
T1 - Chiral biomolecule based dodecanuclear dysprosium(III)-copper(II) clusters
T2 - Structural analyses and magnetic properties
AU - Joarder, Biplab
AU - Mukherjee, Soumya
AU - Patil, Mahendra
AU - Xue, Shufang
AU - Tang, Jinkui
AU - Ghosh, Sujit K.
N1 - Publisher Copyright:
© the Partner Organisations 2015.
PY - 2015/9/1
Y1 - 2015/9/1
N2 - An isostructural family of three dodecanuclear chiral M4Cu8 (M = Dy, Y) complexes has been synthesized by adopting a mixed-ligand strategy, wherein one of the constituent linkers, pyroglutamic acid, a recognized biomolecule, has been credibly functioning as the chiral precursor imparting the chirality to the aforementioned complex. The highly symmetric new-fangled M4Cu8 coordination-core, comprising of four square-symmetrically coordinated Dy/Y-vertex sharing M2Cu2 cubane units, has been synthesized as an unprecedented discrete coordination complex, which has been analysed by magnetic measurements.
AB - An isostructural family of three dodecanuclear chiral M4Cu8 (M = Dy, Y) complexes has been synthesized by adopting a mixed-ligand strategy, wherein one of the constituent linkers, pyroglutamic acid, a recognized biomolecule, has been credibly functioning as the chiral precursor imparting the chirality to the aforementioned complex. The highly symmetric new-fangled M4Cu8 coordination-core, comprising of four square-symmetrically coordinated Dy/Y-vertex sharing M2Cu2 cubane units, has been synthesized as an unprecedented discrete coordination complex, which has been analysed by magnetic measurements.
UR - http://www.scopus.com/inward/record.url?scp=84940376299&partnerID=8YFLogxK
U2 - 10.1039/c5qi00090d
DO - 10.1039/c5qi00090d
M3 - Article
AN - SCOPUS:84940376299
SN - 2052-1553
VL - 2
SP - 854
EP - 859
JO - Inorganic Chemistry Frontiers
JF - Inorganic Chemistry Frontiers
IS - 9
ER -