Chiral biomolecule based dodecanuclear dysprosium(III)-copper(II) clusters: Structural analyses and magnetic properties

Biplab Joarder; Soumya Mukherjee; Mahendra Patil; Shufang Xue; Jinkui Tang; Sujit K. Ghosh

doi:10.1039/c5qi00090d

Chiral biomolecule based dodecanuclear dysprosium(III)-copper(II) clusters: Structural analyses and magnetic properties

Biplab Joarder
, Soumya Mukherjee
, Mahendra Patil
, Shufang Xue
, Jinkui Tang
, Sujit K. Ghosh

Research output: Contribution to journal › Article › peer-review

Abstract

An isostructural family of three dodecanuclear chiral M₄Cu₈ (M = Dy, Y) complexes has been synthesized by adopting a mixed-ligand strategy, wherein one of the constituent linkers, pyroglutamic acid, a recognized biomolecule, has been credibly functioning as the chiral precursor imparting the chirality to the aforementioned complex. The highly symmetric new-fangled M₄Cu₈ coordination-core, comprising of four square-symmetrically coordinated Dy/Y-vertex sharing M₂Cu₂ cubane units, has been synthesized as an unprecedented discrete coordination complex, which has been analysed by magnetic measurements.

Original language	English
Pages (from-to)	854-859
Number of pages	6
Journal	Inorganic Chemistry Frontiers
Volume	2
Issue number	9
DOIs	https://doi.org/10.1039/c5qi00090d
Publication status	Published - 1 Sep 2015
Externally published	Yes

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title = "Chiral biomolecule based dodecanuclear dysprosium(III)-copper(II) clusters: Structural analyses and magnetic properties",

abstract = "An isostructural family of three dodecanuclear chiral M4Cu8 (M = Dy, Y) complexes has been synthesized by adopting a mixed-ligand strategy, wherein one of the constituent linkers, pyroglutamic acid, a recognized biomolecule, has been credibly functioning as the chiral precursor imparting the chirality to the aforementioned complex. The highly symmetric new-fangled M4Cu8 coordination-core, comprising of four square-symmetrically coordinated Dy/Y-vertex sharing M2Cu2 cubane units, has been synthesized as an unprecedented discrete coordination complex, which has been analysed by magnetic measurements.",

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T2 - Structural analyses and magnetic properties

AU - Joarder, Biplab

AU - Mukherjee, Soumya

AU - Patil, Mahendra

AU - Xue, Shufang

AU - Tang, Jinkui

AU - Ghosh, Sujit K.

PY - 2015/9/1

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N2 - An isostructural family of three dodecanuclear chiral M4Cu8 (M = Dy, Y) complexes has been synthesized by adopting a mixed-ligand strategy, wherein one of the constituent linkers, pyroglutamic acid, a recognized biomolecule, has been credibly functioning as the chiral precursor imparting the chirality to the aforementioned complex. The highly symmetric new-fangled M4Cu8 coordination-core, comprising of four square-symmetrically coordinated Dy/Y-vertex sharing M2Cu2 cubane units, has been synthesized as an unprecedented discrete coordination complex, which has been analysed by magnetic measurements.

AB - An isostructural family of three dodecanuclear chiral M4Cu8 (M = Dy, Y) complexes has been synthesized by adopting a mixed-ligand strategy, wherein one of the constituent linkers, pyroglutamic acid, a recognized biomolecule, has been credibly functioning as the chiral precursor imparting the chirality to the aforementioned complex. The highly symmetric new-fangled M4Cu8 coordination-core, comprising of four square-symmetrically coordinated Dy/Y-vertex sharing M2Cu2 cubane units, has been synthesized as an unprecedented discrete coordination complex, which has been analysed by magnetic measurements.

UR - https://www.scopus.com/pages/publications/84940376299

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JO - Inorganic Chemistry Frontiers

JF - Inorganic Chemistry Frontiers

IS - 9

ER -

Chiral biomolecule based dodecanuclear dysprosium(III)-copper(II) clusters: Structural analyses and magnetic properties

Abstract

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