Combinatorial approach to the preparation and characterization of catalysts for biomass steam reforming into syngas

Polina Yaseneva; Svetlana Pavlova; Vladislav Sadykov; Galina Alikina; Anton Lykashevich; Vladimir Rogov; Sergey Belochapkine; Julian Ross

doi:10.1016/j.cattod.2008.03.016

Combinatorial approach to the preparation and characterization of catalysts for biomass steam reforming into syngas

Polina Yaseneva
, Svetlana Pavlova
, Vladislav Sadykov
, Galina Alikina
, Anton Lykashevich
, Vladimir Rogov
, Sergey Belochapkine
, Julian Ross

RAS - Boreskov Institute of Catalysis, Siberian Branch

Research output: Contribution to journal › Article › peer-review

Abstract

A number of catalysts based on Al₂O₃ loaded with doped Ce-Zr mixed oxides and different active components (Cu, Cu-Ni, Ru, Pt, etc.) were synthesized via standard wet impregnation method using the robotic workstation. Ethanol (EtOH) was taken as a model compound of bio-oil and steam reforming of ethanol (ESR)-as a model reaction. Activity screening experiments performed at 600-700 °C in 0.5 vol.% C₂H₅OH + 2.5 vol.% H₂O + 97 vol.% He mixture revealed that the most effective catalyst composition is Ru/Ce_0.4Zr_0.4Sm_0.2/Al₂O₃. Catalytic activity investigations at high reagent concentrations (10 vol.% C₂H₅OH + 40 vol.% H₂O + 50 vol.% N₂) at 650-800 °C confirmed this fact, revealing also that at high temperatures the activity of Cu-Ni catalysts is comparable with that of Ru-containing catalyst.

Original language	English
Pages (from-to)	23-28
Number of pages	6
Journal	Catalysis Today
Volume	137
Issue number	1
DOIs	https://doi.org/10.1016/j.cattod.2008.03.016
Publication status	Published - 30 Aug 2008

Keywords

Bio-oil
Ce-Zr mixed oxides
Combinatorial synthesis
Cu-Ni
Pt
Ru
Steam reforming of ethanol
Syngas

Access to Document

10.1016/j.cattod.2008.03.016

Cite this

@article{8efb422d6a1f4bbd878a4308c53075db,

title = "Combinatorial approach to the preparation and characterization of catalysts for biomass steam reforming into syngas",

abstract = "A number of catalysts based on Al2O3 loaded with doped Ce-Zr mixed oxides and different active components (Cu, Cu-Ni, Ru, Pt, etc.) were synthesized via standard wet impregnation method using the robotic workstation. Ethanol (EtOH) was taken as a model compound of bio-oil and steam reforming of ethanol (ESR)-as a model reaction. Activity screening experiments performed at 600-700 °C in 0.5 vol.\% C2H5OH + 2.5 vol.\% H2O + 97 vol.\% He mixture revealed that the most effective catalyst composition is Ru/Ce0.4Zr0.4Sm0.2/Al2O3. Catalytic activity investigations at high reagent concentrations (10 vol.\% C2H5OH + 40 vol.\% H2O + 50 vol.\% N2) at 650-800 °C confirmed this fact, revealing also that at high temperatures the activity of Cu-Ni catalysts is comparable with that of Ru-containing catalyst.",

keywords = "Bio-oil, Ce-Zr mixed oxides, Combinatorial synthesis, Cu-Ni, Pt, Ru, Steam reforming of ethanol, Syngas",

author = "Polina Yaseneva and Svetlana Pavlova and Vladislav Sadykov and Galina Alikina and Anton Lykashevich and Vladimir Rogov and Sergey Belochapkine and Julian Ross",

year = "2008",

month = aug,

day = "30",

doi = "10.1016/j.cattod.2008.03.016",

language = "English",

volume = "137",

pages = "23--28",

journal = "Catalysis Today",

issn = "0920-5861",

number = "1",

}

TY - JOUR

T1 - Combinatorial approach to the preparation and characterization of catalysts for biomass steam reforming into syngas

AU - Yaseneva, Polina

AU - Pavlova, Svetlana

AU - Sadykov, Vladislav

AU - Alikina, Galina

AU - Lykashevich, Anton

AU - Rogov, Vladimir

AU - Belochapkine, Sergey

AU - Ross, Julian

PY - 2008/8/30

Y1 - 2008/8/30

N2 - A number of catalysts based on Al2O3 loaded with doped Ce-Zr mixed oxides and different active components (Cu, Cu-Ni, Ru, Pt, etc.) were synthesized via standard wet impregnation method using the robotic workstation. Ethanol (EtOH) was taken as a model compound of bio-oil and steam reforming of ethanol (ESR)-as a model reaction. Activity screening experiments performed at 600-700 °C in 0.5 vol.% C2H5OH + 2.5 vol.% H2O + 97 vol.% He mixture revealed that the most effective catalyst composition is Ru/Ce0.4Zr0.4Sm0.2/Al2O3. Catalytic activity investigations at high reagent concentrations (10 vol.% C2H5OH + 40 vol.% H2O + 50 vol.% N2) at 650-800 °C confirmed this fact, revealing also that at high temperatures the activity of Cu-Ni catalysts is comparable with that of Ru-containing catalyst.

AB - A number of catalysts based on Al2O3 loaded with doped Ce-Zr mixed oxides and different active components (Cu, Cu-Ni, Ru, Pt, etc.) were synthesized via standard wet impregnation method using the robotic workstation. Ethanol (EtOH) was taken as a model compound of bio-oil and steam reforming of ethanol (ESR)-as a model reaction. Activity screening experiments performed at 600-700 °C in 0.5 vol.% C2H5OH + 2.5 vol.% H2O + 97 vol.% He mixture revealed that the most effective catalyst composition is Ru/Ce0.4Zr0.4Sm0.2/Al2O3. Catalytic activity investigations at high reagent concentrations (10 vol.% C2H5OH + 40 vol.% H2O + 50 vol.% N2) at 650-800 °C confirmed this fact, revealing also that at high temperatures the activity of Cu-Ni catalysts is comparable with that of Ru-containing catalyst.

KW - Bio-oil

KW - Ce-Zr mixed oxides

KW - Combinatorial synthesis

KW - Cu-Ni

KW - Pt

KW - Ru

KW - Steam reforming of ethanol

KW - Syngas

UR - https://www.scopus.com/pages/publications/45949108895

U2 - 10.1016/j.cattod.2008.03.016

DO - 10.1016/j.cattod.2008.03.016

M3 - Article

AN - SCOPUS:45949108895

SN - 0920-5861

VL - 137

SP - 23

EP - 28

JO - Catalysis Today

JF - Catalysis Today

IS - 1

ER -

Combinatorial approach to the preparation and characterization of catalysts for biomass steam reforming into syngas

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this