Competing Pathways in the Reaction of Bis(pentafluorophenyl)borane with Bis(η5‐cyclopentadienyl)dimethylzirconium: Methane Elimination versus Methyl–Hydride Exchange and an Example of Pentacoordinate Carbon

Rupert E. Rupert; Daniel J. Parks; Warren E. Piers; Mary‐Anne ‐A MacDonald; Michael J. Zaworotko; Steven J. Rettig

doi:10.1002/anie.199512301

Competing Pathways in the Reaction of Bis(pentafluorophenyl)borane with Bis(η⁵‐cyclopentadienyl)dimethylzirconium: Methane Elimination versus Methyl–Hydride Exchange and an Example of Pentacoordinate Carbon

Rupert E. Rupert, Daniel J. Parks, Warren E. Piers, Mary‐Anne ‐A MacDonald, Michael J. Zaworotko, Steven J. Rettig

Research output: Contribution to journal › Article › peer-review

Abstract

The structural isomer of a potentially very active Ziegler–Natta olefin polymerization catalyst 1, is one of the final products in the reaction of [Cp₂ZrMe₂] with the highly electrophilic borane HB(C₆F₅)₂. The most unusual structural feature of 1 is a pentacoordinate carbon atom. Interestingly, 1 is completely unreactive towards ethylene under ambient conditions. (Figure Presented.)

Original language	English
Pages (from-to)	1230-1233
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	34
Issue number	11
DOIs	https://doi.org/10.1002/anie.199512301
Publication status	Published - 16 Jun 1995
Externally published	Yes

Keywords

boranes
catalysis
five‐coordinate carbon
sandwich complexes
zirconium compounds

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Rupert, R. E., Parks, D. J., Piers, W. E., MacDonald, MA. A., Zaworotko, M. J., & Rettig, S. J. (1995). Competing Pathways in the Reaction of Bis(pentafluorophenyl)borane with Bis(η⁵‐cyclopentadienyl)dimethylzirconium: Methane Elimination versus Methyl–Hydride Exchange and an Example of Pentacoordinate Carbon. Angewandte Chemie - International Edition, 34(11), 1230-1233. https://doi.org/10.1002/anie.199512301

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title = "Competing Pathways in the Reaction of Bis(pentafluorophenyl)borane with Bis(η5‐cyclopentadienyl)dimethylzirconium: Methane Elimination versus Methyl–Hydride Exchange and an Example of Pentacoordinate Carbon",

abstract = "The structural isomer of a potentially very active Ziegler–Natta olefin polymerization catalyst 1, is one of the final products in the reaction of [Cp2ZrMe2] with the highly electrophilic borane HB(C6F5)2. The most unusual structural feature of 1 is a pentacoordinate carbon atom. Interestingly, 1 is completely unreactive towards ethylene under ambient conditions. (Figure Presented.)",

keywords = "boranes, catalysis, five‐coordinate carbon, sandwich complexes, zirconium compounds",

author = "Rupert, \{Rupert E.\} and Parks, \{Daniel J.\} and Piers, \{Warren E.\} and MacDonald, \{Mary‐Anne ‐A\} and Zaworotko, \{Michael J.\} and Rettig, \{Steven J.\}",

year = "1995",

month = jun,

day = "16",

doi = "10.1002/anie.199512301",

language = "English",

volume = "34",

pages = "1230--1233",

journal = "Angewandte Chemie - International Edition",

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Rupert, RE, Parks, DJ, Piers, WE, MacDonald, MAA, Zaworotko, MJ & Rettig, SJ 1995, 'Competing Pathways in the Reaction of Bis(pentafluorophenyl)borane with Bis(η⁵‐cyclopentadienyl)dimethylzirconium: Methane Elimination versus Methyl–Hydride Exchange and an Example of Pentacoordinate Carbon', Angewandte Chemie - International Edition, vol. 34, no. 11, pp. 1230-1233. https://doi.org/10.1002/anie.199512301

Competing Pathways in the Reaction of Bis(pentafluorophenyl)borane with Bis(η⁵‐cyclopentadienyl)dimethylzirconium: Methane Elimination versus Methyl–Hydride Exchange and an Example of Pentacoordinate Carbon. / Rupert, Rupert E.; Parks, Daniel J.; Piers, Warren E. et al.
In: Angewandte Chemie - International Edition, Vol. 34, No. 11, 16.06.1995, p. 1230-1233.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Competing Pathways in the Reaction of Bis(pentafluorophenyl)borane with Bis(η5‐cyclopentadienyl)dimethylzirconium

T2 - Methane Elimination versus Methyl–Hydride Exchange and an Example of Pentacoordinate Carbon

AU - Rupert, Rupert E.

AU - Parks, Daniel J.

AU - Piers, Warren E.

AU - MacDonald, Mary‐Anne ‐A

AU - Zaworotko, Michael J.

AU - Rettig, Steven J.

PY - 1995/6/16

Y1 - 1995/6/16

N2 - The structural isomer of a potentially very active Ziegler–Natta olefin polymerization catalyst 1, is one of the final products in the reaction of [Cp2ZrMe2] with the highly electrophilic borane HB(C6F5)2. The most unusual structural feature of 1 is a pentacoordinate carbon atom. Interestingly, 1 is completely unreactive towards ethylene under ambient conditions. (Figure Presented.)

AB - The structural isomer of a potentially very active Ziegler–Natta olefin polymerization catalyst 1, is one of the final products in the reaction of [Cp2ZrMe2] with the highly electrophilic borane HB(C6F5)2. The most unusual structural feature of 1 is a pentacoordinate carbon atom. Interestingly, 1 is completely unreactive towards ethylene under ambient conditions. (Figure Presented.)

KW - boranes

KW - catalysis

KW - five‐coordinate carbon

KW - sandwich complexes

KW - zirconium compounds

UR - https://www.scopus.com/pages/publications/33748231519

U2 - 10.1002/anie.199512301

DO - 10.1002/anie.199512301

M3 - Article

AN - SCOPUS:33748231519

SN - 0570-0833

VL - 34

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JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 11

ER -

Rupert RE, Parks DJ, Piers WE, MacDonald MAA, Zaworotko MJ, Rettig SJ. Competing Pathways in the Reaction of Bis(pentafluorophenyl)borane with Bis(η⁵‐cyclopentadienyl)dimethylzirconium: Methane Elimination versus Methyl–Hydride Exchange and an Example of Pentacoordinate Carbon. Angewandte Chemie - International Edition. 1995 Jun 16;34(11):1230-1233. doi: 10.1002/anie.199512301