TY - JOUR
T1 - Construction of a Series of Porous (3,9)-c Coordination Networks Using Dicarboxylate and Tris-pyridyl Ligands and Their Gas Storage Properties
AU - Hua, Carol
AU - Yang, Qing Yuan
AU - Zaworotko, Michael J.
N1 - Publisher Copyright:
© 2017 American Chemical Society.
PY - 2017/6/7
Y1 - 2017/6/7
N2 - A series of isostructural coordination networks of formula [M2IIMIII(μ-OH)(NPy3)(bpdc)3]·xsolvent (M = Co, Ni, Fe) that exhibit a noninterpenetrated binodal (3,9)-net, the first reported hua topology networks, have been constructed from a 3-c ligand, tris(4-(4-pyridin-4-yl)phenyl)amine (NPy3), and a previously known 9-c trinuclear metal carboxylate cluster. The (3,9)-nets exhibit high void space and large uptake capacity for the high pressure storage of CH4 and CO2.
AB - A series of isostructural coordination networks of formula [M2IIMIII(μ-OH)(NPy3)(bpdc)3]·xsolvent (M = Co, Ni, Fe) that exhibit a noninterpenetrated binodal (3,9)-net, the first reported hua topology networks, have been constructed from a 3-c ligand, tris(4-(4-pyridin-4-yl)phenyl)amine (NPy3), and a previously known 9-c trinuclear metal carboxylate cluster. The (3,9)-nets exhibit high void space and large uptake capacity for the high pressure storage of CH4 and CO2.
UR - http://www.scopus.com/inward/record.url?scp=85020297531&partnerID=8YFLogxK
U2 - 10.1021/acs.cgd.7b00451
DO - 10.1021/acs.cgd.7b00451
M3 - Article
AN - SCOPUS:85020297531
SN - 1528-7483
VL - 17
SP - 3475
EP - 3481
JO - Crystal Growth and Design
JF - Crystal Growth and Design
IS - 6
ER -