Construction of a Series of Porous (3,9)-c Coordination Networks Using Dicarboxylate and Tris-pyridyl Ligands and Their Gas Storage Properties

Carol Hua; Qing Yuan Yang; Michael J. Zaworotko

doi:10.1021/acs.cgd.7b00451

Construction of a Series of Porous (3,9)-c Coordination Networks Using Dicarboxylate and Tris-pyridyl Ligands and Their Gas Storage Properties

Carol Hua
, Qing Yuan Yang
, Michael J. Zaworotko

University of Limerick

Research output: Contribution to journal › Article › peer-review

Abstract

A series of isostructural coordination networks of formula [M₂^IIM^III(μ-OH)(NPy₃)(bpdc)₃]·xsolvent (M = Co, Ni, Fe) that exhibit a noninterpenetrated binodal (3,9)-net, the first reported hua topology networks, have been constructed from a 3-c ligand, tris(4-(4-pyridin-4-yl)phenyl)amine (NPy₃), and a previously known 9-c trinuclear metal carboxylate cluster. The (3,9)-nets exhibit high void space and large uptake capacity for the high pressure storage of CH₄ and CO₂.

Original language	English
Pages (from-to)	3475-3481
Number of pages	7
Journal	Crystal Growth and Design
Volume	17
Issue number	6
DOIs	https://doi.org/10.1021/acs.cgd.7b00451
Publication status	Published - 7 Jun 2017

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title = "Construction of a Series of Porous (3,9)-c Coordination Networks Using Dicarboxylate and Tris-pyridyl Ligands and Their Gas Storage Properties",

abstract = "A series of isostructural coordination networks of formula [M2IIMIII(μ-OH)(NPy3)(bpdc)3]·xsolvent (M = Co, Ni, Fe) that exhibit a noninterpenetrated binodal (3,9)-net, the first reported hua topology networks, have been constructed from a 3-c ligand, tris(4-(4-pyridin-4-yl)phenyl)amine (NPy3), and a previously known 9-c trinuclear metal carboxylate cluster. The (3,9)-nets exhibit high void space and large uptake capacity for the high pressure storage of CH4 and CO2.",

author = "Carol Hua and Yang, \{Qing Yuan\} and Zaworotko, \{Michael J.\}",

note = "Publisher Copyright: {\textcopyright} 2017 American Chemical Society.",

year = "2017",

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doi = "10.1021/acs.cgd.7b00451",

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AU - Hua, Carol

AU - Yang, Qing Yuan

AU - Zaworotko, Michael J.

PY - 2017/6/7

Y1 - 2017/6/7

N2 - A series of isostructural coordination networks of formula [M2IIMIII(μ-OH)(NPy3)(bpdc)3]·xsolvent (M = Co, Ni, Fe) that exhibit a noninterpenetrated binodal (3,9)-net, the first reported hua topology networks, have been constructed from a 3-c ligand, tris(4-(4-pyridin-4-yl)phenyl)amine (NPy3), and a previously known 9-c trinuclear metal carboxylate cluster. The (3,9)-nets exhibit high void space and large uptake capacity for the high pressure storage of CH4 and CO2.

AB - A series of isostructural coordination networks of formula [M2IIMIII(μ-OH)(NPy3)(bpdc)3]·xsolvent (M = Co, Ni, Fe) that exhibit a noninterpenetrated binodal (3,9)-net, the first reported hua topology networks, have been constructed from a 3-c ligand, tris(4-(4-pyridin-4-yl)phenyl)amine (NPy3), and a previously known 9-c trinuclear metal carboxylate cluster. The (3,9)-nets exhibit high void space and large uptake capacity for the high pressure storage of CH4 and CO2.

UR - https://www.scopus.com/pages/publications/85020297531

U2 - 10.1021/acs.cgd.7b00451

DO - 10.1021/acs.cgd.7b00451

M3 - Article

AN - SCOPUS:85020297531

SN - 1528-7483

VL - 17

SP - 3475

EP - 3481

JO - Crystal Growth and Design

JF - Crystal Growth and Design

IS - 6

ER -

Construction of a Series of Porous (3,9)-c Coordination Networks Using Dicarboxylate and Tris-pyridyl Ligands and Their Gas Storage Properties

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