Crystal engineering of a calix-arene dimer embedded in a hydrophobic cavity formed by a diammonium host matrix

Beth Rather; Brian Moulton; Michael J. Zaworotko; Florent Perret; Nicole Morel-Desrosiers; Eric Da Silva; Anthony W. Coleman

doi:10.1016/S1463-0184(03)00047-9

Crystal engineering of a calix-arene dimer embedded in a hydrophobic cavity formed by a diammonium host matrix

Beth Rather, Brian Moulton, Michael J. Zaworotko, Florent Perret, Nicole Morel-Desrosiers, Eric Da Silva, Anthony W. Coleman

Research output: Contribution to journal › Article › peer-review

Abstract

The crystal structure of the 2:1 1, 6-diamino-hexane: para-H-calix-4-arene-25, 27-di-phosphonate complex was examined. The analysis showed a designed encapsulation of a calix-arene dimer within a three-dimensional matrix formed by the diamine molecules. It was also found that the slight mismatch in the length of the diamine molecules compared to the size of the calix-arene molecule was compensated by chain folding in the diamine.

Original language	English
Pages (from-to)	15-21
Number of pages	7
Journal	Crystal Engineering
Volume	6
Issue number	1
DOIs	https://doi.org/10.1016/S1463-0184(03)00047-9
Publication status	Published - Mar 2003
Externally published	Yes

Keywords

Calixarene
Crystal structure
Hydrogen bond

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10.1016/S1463-0184(03)00047-9

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title = "Crystal engineering of a calix-arene dimer embedded in a hydrophobic cavity formed by a diammonium host matrix",

abstract = "The crystal structure of the 2:1 1, 6-diamino-hexane: para-H-calix-4-arene-25, 27-di-phosphonate complex was examined. The analysis showed a designed encapsulation of a calix-arene dimer within a three-dimensional matrix formed by the diamine molecules. It was also found that the slight mismatch in the length of the diamine molecules compared to the size of the calix-arene molecule was compensated by chain folding in the diamine.",

keywords = "Calixarene, Crystal structure, Hydrogen bond",

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year = "2003",

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T1 - Crystal engineering of a calix-arene dimer embedded in a hydrophobic cavity formed by a diammonium host matrix

AU - Rather, Beth

AU - Moulton, Brian

AU - Zaworotko, Michael J.

AU - Perret, Florent

AU - Morel-Desrosiers, Nicole

AU - Da Silva, Eric

AU - Coleman, Anthony W.

PY - 2003/3

Y1 - 2003/3

N2 - The crystal structure of the 2:1 1, 6-diamino-hexane: para-H-calix-4-arene-25, 27-di-phosphonate complex was examined. The analysis showed a designed encapsulation of a calix-arene dimer within a three-dimensional matrix formed by the diamine molecules. It was also found that the slight mismatch in the length of the diamine molecules compared to the size of the calix-arene molecule was compensated by chain folding in the diamine.

AB - The crystal structure of the 2:1 1, 6-diamino-hexane: para-H-calix-4-arene-25, 27-di-phosphonate complex was examined. The analysis showed a designed encapsulation of a calix-arene dimer within a three-dimensional matrix formed by the diamine molecules. It was also found that the slight mismatch in the length of the diamine molecules compared to the size of the calix-arene molecule was compensated by chain folding in the diamine.

KW - Calixarene

KW - Crystal structure

KW - Hydrogen bond

UR - http://www.scopus.com/inward/record.url?scp=0344921330&partnerID=8YFLogxK

U2 - 10.1016/S1463-0184(03)00047-9

DO - 10.1016/S1463-0184(03)00047-9

M3 - Article

AN - SCOPUS:0344921330

SN - 1463-0184

VL - 6

SP - 15

EP - 21

JO - Crystal Engineering

JF - Crystal Engineering

IS - 1

ER -

Crystal engineering of a calix-arene dimer embedded in a hydrophobic cavity formed by a diammonium host matrix

Abstract

Keywords

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