Crystal engineering of a microporous, catalytically active fcu topology MOF using a custom-designed metalloporphyrin linker

Le Meng; Qigan Cheng; Chungsik Kim; Wen Yang Gao; Lukasz Wojtas; Yu Sheng Chen; Michael J. Zaworotko; X. Peter Zhang; Shengqian Ma

doi:10.1002/anie.201205603

Crystal engineering of a microporous, catalytically active fcu topology MOF using a custom-designed metalloporphyrin linker

Le Meng
, Qigan Cheng
, Chungsik Kim
, Wen Yang Gao
, Lukasz Wojtas
, Yu Sheng Chen
, Michael J. Zaworotko
, X. Peter Zhang
, Shengqian Ma

Research output: Contribution to journal › Article › peer-review

Abstract

A 12-connected fcu metal-organic framework (MOF), MMPF-3, has been prepared using a Co ^II metalloporphyrin. MMPF-3 is comprised of the same polyhedral supermolecular building blocks as the prototypal fcu-MOF, fcu-MOF-1, and its nanoscale cavities feature 18 catalytically active cobalt centers. The high density (ca. 5 cobalt sites/nm ³) affords MMPF-3 superior performance in catalytic epoxidation of trans-stilbene compared to other MOFs.

Original language	English
Pages (from-to)	10082-10085
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	51
Issue number	40
DOIs	https://doi.org/10.1002/anie.201205603
Publication status	Published - 1 Oct 2012
Externally published	Yes

Keywords

Metal-organic frameworks
cobalt
crystal engineering
heterogeneous catalysis
metalloporphyrins

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10.1002/anie.201205603

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title = "Crystal engineering of a microporous, catalytically active fcu topology MOF using a custom-designed metalloporphyrin linker",

abstract = "A 12-connected fcu metal-organic framework (MOF), MMPF-3, has been prepared using a Co II metalloporphyrin. MMPF-3 is comprised of the same polyhedral supermolecular building blocks as the prototypal fcu-MOF, fcu-MOF-1, and its nanoscale cavities feature 18 catalytically active cobalt centers. The high density (ca. 5 cobalt sites/nm 3) affords MMPF-3 superior performance in catalytic epoxidation of trans-stilbene compared to other MOFs.",

keywords = "Metal-organic frameworks, cobalt, crystal engineering, heterogeneous catalysis, metalloporphyrins",

author = "Le Meng and Qigan Cheng and Chungsik Kim and Gao, \{Wen Yang\} and Lukasz Wojtas and Chen, \{Yu Sheng\} and Zaworotko, \{Michael J.\} and Zhang, \{X. Peter\} and Shengqian Ma",

year = "2012",

month = oct,

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doi = "10.1002/anie.201205603",

language = "English",

volume = "51",

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journal = "Angewandte Chemie - International Edition",

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TY - JOUR

T1 - Crystal engineering of a microporous, catalytically active fcu topology MOF using a custom-designed metalloporphyrin linker

AU - Meng, Le

AU - Cheng, Qigan

AU - Kim, Chungsik

AU - Gao, Wen Yang

AU - Wojtas, Lukasz

AU - Chen, Yu Sheng

AU - Zaworotko, Michael J.

AU - Zhang, X. Peter

AU - Ma, Shengqian

PY - 2012/10/1

Y1 - 2012/10/1

N2 - A 12-connected fcu metal-organic framework (MOF), MMPF-3, has been prepared using a Co II metalloporphyrin. MMPF-3 is comprised of the same polyhedral supermolecular building blocks as the prototypal fcu-MOF, fcu-MOF-1, and its nanoscale cavities feature 18 catalytically active cobalt centers. The high density (ca. 5 cobalt sites/nm 3) affords MMPF-3 superior performance in catalytic epoxidation of trans-stilbene compared to other MOFs.

AB - A 12-connected fcu metal-organic framework (MOF), MMPF-3, has been prepared using a Co II metalloporphyrin. MMPF-3 is comprised of the same polyhedral supermolecular building blocks as the prototypal fcu-MOF, fcu-MOF-1, and its nanoscale cavities feature 18 catalytically active cobalt centers. The high density (ca. 5 cobalt sites/nm 3) affords MMPF-3 superior performance in catalytic epoxidation of trans-stilbene compared to other MOFs.

KW - Metal-organic frameworks

KW - cobalt

KW - crystal engineering

KW - heterogeneous catalysis

KW - metalloporphyrins

UR - https://www.scopus.com/pages/publications/84867026808

U2 - 10.1002/anie.201205603

DO - 10.1002/anie.201205603

M3 - Article

AN - SCOPUS:84867026808

SN - 1433-7851

VL - 51

SP - 10082

EP - 10085

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 40

ER -

Crystal engineering of a microporous, catalytically active fcu topology MOF using a custom-designed metalloporphyrin linker

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Keywords

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