TY - JOUR
T1 - Crystal engineering of dichromate pillared hybrid ultramicroporous materials incorporating pyrazole-based ligands
AU - Scott, Hayley S.
AU - Mukherjee, Soumya
AU - Turner, David R.
AU - Polson, Matthew I.J.
AU - Zaworotko, Michael J.
AU - Kruger, Paul E.
N1 - Publisher Copyright:
© 2018 The Royal Society of Chemistry.
PY - 2018
Y1 - 2018
N2 - Two new coordination networks of formula [Cu(L)2(Cr2O7)], DICRO-L-Cu, (L = 7: 4-(3,5-dimethyl-1H-pyrazol-4-yl)pyridine; 8: 3,3′,5,5′-tetramethyl-1H,1′H-4,4′-bipyrazole) are reported. These compounds represent the first examples of hybrid ultramicroporous materials incorporating pyrazole-based ligands. Ligand length and sterics mitigate against interpenetration between networks, generating internal voids which have been studied in terms of CO2 and N2 sorption.
AB - Two new coordination networks of formula [Cu(L)2(Cr2O7)], DICRO-L-Cu, (L = 7: 4-(3,5-dimethyl-1H-pyrazol-4-yl)pyridine; 8: 3,3′,5,5′-tetramethyl-1H,1′H-4,4′-bipyrazole) are reported. These compounds represent the first examples of hybrid ultramicroporous materials incorporating pyrazole-based ligands. Ligand length and sterics mitigate against interpenetration between networks, generating internal voids which have been studied in terms of CO2 and N2 sorption.
UR - http://www.scopus.com/inward/record.url?scp=85042643592&partnerID=8YFLogxK
U2 - 10.1039/c8ce00149a
DO - 10.1039/c8ce00149a
M3 - Article
AN - SCOPUS:85042643592
SN - 1466-8033
VL - 20
SP - 1193
EP - 1197
JO - CrystEngComm
JF - CrystEngComm
IS - 9
ER -