Crystal engineering of dichromate pillared hybrid ultramicroporous materials incorporating pyrazole-based ligands

Hayley S. Scott; Soumya Mukherjee; David R. Turner; Matthew I.J. Polson; Michael J. Zaworotko; Paul E. Kruger

doi:10.1039/c8ce00149a

Crystal engineering of dichromate pillared hybrid ultramicroporous materials incorporating pyrazole-based ligands

Hayley S. Scott
, Soumya Mukherjee
, David R. Turner
, Matthew I.J. Polson
, Michael J. Zaworotko
, Paul E. Kruger

Research output: Contribution to journal › Article › peer-review

Abstract

Two new coordination networks of formula [Cu(L)₂(Cr₂O₇)], DICRO-L-Cu, (L = 7: 4-(3,5-dimethyl-1H-pyrazol-4-yl)pyridine; 8: 3,3′,5,5′-tetramethyl-1H,1′H-4,4′-bipyrazole) are reported. These compounds represent the first examples of hybrid ultramicroporous materials incorporating pyrazole-based ligands. Ligand length and sterics mitigate against interpenetration between networks, generating internal voids which have been studied in terms of CO₂ and N₂ sorption.

Original language	English
Pages (from-to)	1193-1197
Number of pages	5
Journal	CrystEngComm
Volume	20
Issue number	9
DOIs	https://doi.org/10.1039/c8ce00149a
Publication status	Published - 2018

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title = "Crystal engineering of dichromate pillared hybrid ultramicroporous materials incorporating pyrazole-based ligands",

abstract = "Two new coordination networks of formula [Cu(L)2(Cr2O7)], DICRO-L-Cu, (L = 7: 4-(3,5-dimethyl-1H-pyrazol-4-yl)pyridine; 8: 3,3′,5,5′-tetramethyl-1H,1′H-4,4′-bipyrazole) are reported. These compounds represent the first examples of hybrid ultramicroporous materials incorporating pyrazole-based ligands. Ligand length and sterics mitigate against interpenetration between networks, generating internal voids which have been studied in terms of CO2 and N2 sorption.",

author = "Scott, \{Hayley S.\} and Soumya Mukherjee and Turner, \{David R.\} and Polson, \{Matthew I.J.\} and Zaworotko, \{Michael J.\} and Kruger, \{Paul E.\}",

note = "Publisher Copyright: {\textcopyright} 2018 The Royal Society of Chemistry.",

year = "2018",

doi = "10.1039/c8ce00149a",

language = "English",

volume = "20",

pages = "1193--1197",

journal = "CrystEngComm",

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T1 - Crystal engineering of dichromate pillared hybrid ultramicroporous materials incorporating pyrazole-based ligands

AU - Scott, Hayley S.

AU - Mukherjee, Soumya

AU - Turner, David R.

AU - Polson, Matthew I.J.

AU - Zaworotko, Michael J.

AU - Kruger, Paul E.

PY - 2018

Y1 - 2018

N2 - Two new coordination networks of formula [Cu(L)2(Cr2O7)], DICRO-L-Cu, (L = 7: 4-(3,5-dimethyl-1H-pyrazol-4-yl)pyridine; 8: 3,3′,5,5′-tetramethyl-1H,1′H-4,4′-bipyrazole) are reported. These compounds represent the first examples of hybrid ultramicroporous materials incorporating pyrazole-based ligands. Ligand length and sterics mitigate against interpenetration between networks, generating internal voids which have been studied in terms of CO2 and N2 sorption.

AB - Two new coordination networks of formula [Cu(L)2(Cr2O7)], DICRO-L-Cu, (L = 7: 4-(3,5-dimethyl-1H-pyrazol-4-yl)pyridine; 8: 3,3′,5,5′-tetramethyl-1H,1′H-4,4′-bipyrazole) are reported. These compounds represent the first examples of hybrid ultramicroporous materials incorporating pyrazole-based ligands. Ligand length and sterics mitigate against interpenetration between networks, generating internal voids which have been studied in terms of CO2 and N2 sorption.

UR - https://www.scopus.com/pages/publications/85042643592

U2 - 10.1039/c8ce00149a

DO - 10.1039/c8ce00149a

M3 - Article

AN - SCOPUS:85042643592

SN - 1466-8033

VL - 20

SP - 1193

EP - 1197

JO - CrystEngComm

JF - CrystEngComm

IS - 9

ER -

Crystal engineering of dichromate pillared hybrid ultramicroporous materials incorporating pyrazole-based ligands

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