TY - JOUR
T1 - Crystal engineering of porous coordination networks for C3 hydrocarbon separation
AU - Gao, Mei Yan
AU - Song, Bai Qiao
AU - Sensharma, Debobroto
AU - Zaworotko, Michael J.
N1 - Publisher Copyright:
© 2020 The Authors. SmartMat published by Tianjin University and John Wiley & Sons Australia, Ltd.
PY - 2021/3
Y1 - 2021/3
N2 - C3 hydrocarbons (HCs), especially propylene and propane, are high-volume products of the chemical industry as they are utilized for the production of fuels, polymers, and chemical commodities. Demand for C3 HCs as chemical building blocks is increasing but obtaining them in sufficient purity (>99.95%) for polymer and chemical processes requires economically and energetically costly methods such as cryogenic distillation. Adsorptive separations using porous coordination networks (PCNs) could offer an energy-efficient alternative to current technologies for C3 HC purification because of the lower energy footprint of sorbent separations for recycling versus alternatives such as distillation, solvent extraction, and chemical transformation. In this review, we address how the structural modularity of porous PCNs makes them amenable to crystal engineering that in turn enables control over pore size, shape, and chemistry. We detail how control over pore structure has enabled PCN sorbents to offer benchmark performance for C3 separations thanks to several distinct mechanisms, each of which is highlighted. We also discuss the major challenges and opportunities that remain to be addressed before the commercial development of PCNs as advanced sorbents for C3 separation becomes viable.
AB - C3 hydrocarbons (HCs), especially propylene and propane, are high-volume products of the chemical industry as they are utilized for the production of fuels, polymers, and chemical commodities. Demand for C3 HCs as chemical building blocks is increasing but obtaining them in sufficient purity (>99.95%) for polymer and chemical processes requires economically and energetically costly methods such as cryogenic distillation. Adsorptive separations using porous coordination networks (PCNs) could offer an energy-efficient alternative to current technologies for C3 HC purification because of the lower energy footprint of sorbent separations for recycling versus alternatives such as distillation, solvent extraction, and chemical transformation. In this review, we address how the structural modularity of porous PCNs makes them amenable to crystal engineering that in turn enables control over pore size, shape, and chemistry. We detail how control over pore structure has enabled PCN sorbents to offer benchmark performance for C3 separations thanks to several distinct mechanisms, each of which is highlighted. We also discuss the major challenges and opportunities that remain to be addressed before the commercial development of PCNs as advanced sorbents for C3 separation becomes viable.
KW - binding sites
KW - C3 hydrocarbon
KW - PCNs
KW - separation
UR - http://www.scopus.com/inward/record.url?scp=85111475044&partnerID=8YFLogxK
U2 - 10.1002/smm2.1016
DO - 10.1002/smm2.1016
M3 - Review article
AN - SCOPUS:85111475044
SN - 2766-8525
VL - 2
SP - 38
EP - 55
JO - SmartMat
JF - SmartMat
IS - 1
ER -