Demonstration of surface plasmon-coupled emission using solid-state electrochemiluminescence

Jong Seol Yuk; Emmet O'Reilly; Robert J. Forster; Brian D. MacCraith; Colette McDonagh

doi:10.1016/j.cplett.2011.07.083

Demonstration of surface plasmon-coupled emission using solid-state electrochemiluminescence

Jong Seol Yuk
, Emmet O'Reilly
, Robert J. Forster
, Brian D. MacCraith
, Colette McDonagh

Dublin City University

Research output: Contribution to journal › Article › peer-review

Abstract

We have presented novel surface plasmon-coupled emission (SPCE) based on solid-state electrochemiluminescence (ECL) of Nafion films containing tris(2,2′-bipyridyl)ruthenium(II). This approach combines the advantages of ECL, efficient emission in the absence of an external light source, with the highly directional emission of SPCE. We described theoretical calculations and optimal Nafion film thickness to get SPCE based on solid-state ECL. We confirmed the SPCE and dose-dependent SPCE response from the concentration range of 0.05-0.5% (w/v) [Ru(bpy)₃]²⁺ in the Nafion film. SPCE based on solid-state ECL can be used as a useful platform for the analysis of chemical and biomolecular interactions.

Original language	English
Pages (from-to)	112-117
Number of pages	6
Journal	Chemical Physics Letters
Volume	513
Issue number	1-3
DOIs	https://doi.org/10.1016/j.cplett.2011.07.083
Publication status	Published - 6 Sept 2011
Externally published	Yes

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10.1016/j.cplett.2011.07.083

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@article{25dd8e1c9b96419185acd8f10f66de46,

title = "Demonstration of surface plasmon-coupled emission using solid-state electrochemiluminescence",

abstract = "We have presented novel surface plasmon-coupled emission (SPCE) based on solid-state electrochemiluminescence (ECL) of Nafion films containing tris(2,2′-bipyridyl)ruthenium(II). This approach combines the advantages of ECL, efficient emission in the absence of an external light source, with the highly directional emission of SPCE. We described theoretical calculations and optimal Nafion film thickness to get SPCE based on solid-state ECL. We confirmed the SPCE and dose-dependent SPCE response from the concentration range of 0.05-0.5\% (w/v) [Ru(bpy)3]2+ in the Nafion film. SPCE based on solid-state ECL can be used as a useful platform for the analysis of chemical and biomolecular interactions.",

author = "Yuk, \{Jong Seol\} and Emmet O'Reilly and Forster, \{Robert J.\} and MacCraith, \{Brian D.\} and Colette McDonagh",

year = "2011",

month = sep,

day = "6",

doi = "10.1016/j.cplett.2011.07.083",

language = "English",

volume = "513",

pages = "112--117",

journal = "Chemical Physics Letters",

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TY - JOUR

T1 - Demonstration of surface plasmon-coupled emission using solid-state electrochemiluminescence

AU - Yuk, Jong Seol

AU - O'Reilly, Emmet

AU - Forster, Robert J.

AU - MacCraith, Brian D.

AU - McDonagh, Colette

PY - 2011/9/6

Y1 - 2011/9/6

N2 - We have presented novel surface plasmon-coupled emission (SPCE) based on solid-state electrochemiluminescence (ECL) of Nafion films containing tris(2,2′-bipyridyl)ruthenium(II). This approach combines the advantages of ECL, efficient emission in the absence of an external light source, with the highly directional emission of SPCE. We described theoretical calculations and optimal Nafion film thickness to get SPCE based on solid-state ECL. We confirmed the SPCE and dose-dependent SPCE response from the concentration range of 0.05-0.5% (w/v) [Ru(bpy)3]2+ in the Nafion film. SPCE based on solid-state ECL can be used as a useful platform for the analysis of chemical and biomolecular interactions.

AB - We have presented novel surface plasmon-coupled emission (SPCE) based on solid-state electrochemiluminescence (ECL) of Nafion films containing tris(2,2′-bipyridyl)ruthenium(II). This approach combines the advantages of ECL, efficient emission in the absence of an external light source, with the highly directional emission of SPCE. We described theoretical calculations and optimal Nafion film thickness to get SPCE based on solid-state ECL. We confirmed the SPCE and dose-dependent SPCE response from the concentration range of 0.05-0.5% (w/v) [Ru(bpy)3]2+ in the Nafion film. SPCE based on solid-state ECL can be used as a useful platform for the analysis of chemical and biomolecular interactions.

UR - https://www.scopus.com/pages/publications/80052259331

U2 - 10.1016/j.cplett.2011.07.083

DO - 10.1016/j.cplett.2011.07.083

M3 - Article

AN - SCOPUS:80052259331

SN - 0009-2614

VL - 513

SP - 112

EP - 117

JO - Chemical Physics Letters

JF - Chemical Physics Letters

IS - 1-3

ER -

Demonstration of surface plasmon-coupled emission using solid-state electrochemiluminescence

Abstract

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