TY - GEN
T1 - Design and pilot scale tests of monolithic catalysts for autotermal/steam reforming of natural gas and biofuels
AU - Beloshapkin, Sergey
AU - Ross, Julian
AU - Sadykov, Vladislav
AU - Mezentseva, Natalia
AU - Alikina, Galina
AU - Vostrikov, Zakhar
AU - Fedorova, Yulia
AU - Pelipenko, Vladimir
AU - Usoltsev, Vladimir
AU - Tikhov, Sergey
AU - Smorygo, Oleg
AU - Ulyanitskii, Vladimir
PY - 2008
Y1 - 2008
N2 - Transformation of fuels (fossil fuel and biofuels) into synthesis gas (syngas) or hydrogen is one of the most important tasks of catalysis in the energy-related fields. Catalysts comprised of precious metals and/or Ni supported on complex oxides with a high lattice oxygen mobility are very efficient and stable to coking in autothermal/steam reforming of various fuels including oxygenates. Monolithic substrates with a good thermal conductivity are promising for providing an efficient heat transfer within the reactor to prevent emergence of hot spots/cool zones deteriorating performance. Results of research aimed on design of such catalysts and characterization of their performance parameters at the pilot-scale level are presented. Structured catalysts comprised of complex fluorite-like/perovskite-like oxides supported on heat-conducting metal/cermet substrates and promoted by precious metals and/or Ni possess a high and stable performance in steam reforming of CH4 and biofuels. This offers new possibilities for transformation of a broad range of fossil and biofuels into syngas for the energy field. This is an abstract of a paper presented at the 2009 AIChE Spring National Meeting and 5th Global Congress on Process Safety (Tampa, FL 4/26-30/2009).
AB - Transformation of fuels (fossil fuel and biofuels) into synthesis gas (syngas) or hydrogen is one of the most important tasks of catalysis in the energy-related fields. Catalysts comprised of precious metals and/or Ni supported on complex oxides with a high lattice oxygen mobility are very efficient and stable to coking in autothermal/steam reforming of various fuels including oxygenates. Monolithic substrates with a good thermal conductivity are promising for providing an efficient heat transfer within the reactor to prevent emergence of hot spots/cool zones deteriorating performance. Results of research aimed on design of such catalysts and characterization of their performance parameters at the pilot-scale level are presented. Structured catalysts comprised of complex fluorite-like/perovskite-like oxides supported on heat-conducting metal/cermet substrates and promoted by precious metals and/or Ni possess a high and stable performance in steam reforming of CH4 and biofuels. This offers new possibilities for transformation of a broad range of fossil and biofuels into syngas for the energy field. This is an abstract of a paper presented at the 2009 AIChE Spring National Meeting and 5th Global Congress on Process Safety (Tampa, FL 4/26-30/2009).
UR - http://www.scopus.com/inward/record.url?scp=78049327685&partnerID=8YFLogxK
M3 - Conference contribution
AN - SCOPUS:78049327685
SN - 9780816910526
T3 - Conference Proceedings - 2009 AIChE Spring National Meeting and 5th Global Congress on Process Safety
BT - Conference Proceedings - 2009 AIChE Spring National Meeting and 5th Global Congress on Process Safety
T2 - 2009 AIChE Spring National Meeting and 5th Global Congress on Process Safety
Y2 - 26 April 2009 through 30 April 2009
ER -
