Double molecular encapsulation of tetrahydrofuran by an amphiphilic calix-[4]-arene

Patrick Shahgaldian; Anthony W. Coleman; Beth Rather; Michael J. Zaworotko

doi:10.1007/s10847-004-7455-1

Double molecular encapsulation of tetrahydrofuran by an amphiphilic calix-[4]-arene

Patrick Shahgaldian, Anthony W. Coleman, Beth Rather, Michael J. Zaworotko

Research output: Contribution to journal › Article › peer-review

Abstract

The crystal structure of para-octanoylcalix-[4]-arene•2 tetrahydrofuran complex reveals double inclusion of the guest molecules, one deep in the aromatic cavity and the other held in a four-fingered molecular hand formed by the aliphatic chains, the inclusion changes the molecular packing from a bilayer system in the absence of guest, to a head-to-tail antiparallel chain packing.

Original language	English
Pages (from-to)	241-245
Number of pages	5
Journal	Journal of Inclusion Phenomena and Macrocyclic Chemistry
Volume	52
Issue number	3-4
DOIs	https://doi.org/10.1007/s10847-004-7455-1
Publication status	Published - Aug 2005
Externally published	Yes

Keywords

Amphiphilic
Calix-[4]-arene
Crystal structure
Double inclusion
Tetrahydrofuran

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10.1007/s10847-004-7455-1

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title = "Double molecular encapsulation of tetrahydrofuran by an amphiphilic calix-[4]-arene",

abstract = "The crystal structure of para-octanoylcalix-[4]-arene•2 tetrahydrofuran complex reveals double inclusion of the guest molecules, one deep in the aromatic cavity and the other held in a four-fingered molecular hand formed by the aliphatic chains, the inclusion changes the molecular packing from a bilayer system in the absence of guest, to a head-to-tail antiparallel chain packing.",

keywords = "Amphiphilic, Calix-[4]-arene, Crystal structure, Double inclusion, Tetrahydrofuran",

author = "Patrick Shahgaldian and Coleman, \{Anthony W.\} and Beth Rather and Zaworotko, \{Michael J.\}",

year = "2005",

month = aug,

doi = "10.1007/s10847-004-7455-1",

language = "English",

volume = "52",

pages = "241--245",

journal = "Journal of Inclusion Phenomena and Macrocyclic Chemistry",

issn = "0923-0750",

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AU - Shahgaldian, Patrick

AU - Coleman, Anthony W.

AU - Rather, Beth

AU - Zaworotko, Michael J.

PY - 2005/8

Y1 - 2005/8

N2 - The crystal structure of para-octanoylcalix-[4]-arene•2 tetrahydrofuran complex reveals double inclusion of the guest molecules, one deep in the aromatic cavity and the other held in a four-fingered molecular hand formed by the aliphatic chains, the inclusion changes the molecular packing from a bilayer system in the absence of guest, to a head-to-tail antiparallel chain packing.

AB - The crystal structure of para-octanoylcalix-[4]-arene•2 tetrahydrofuran complex reveals double inclusion of the guest molecules, one deep in the aromatic cavity and the other held in a four-fingered molecular hand formed by the aliphatic chains, the inclusion changes the molecular packing from a bilayer system in the absence of guest, to a head-to-tail antiparallel chain packing.

KW - Amphiphilic

KW - Calix-[4]-arene

KW - Crystal structure

KW - Double inclusion

KW - Tetrahydrofuran

UR - https://www.scopus.com/pages/publications/21744437173

U2 - 10.1007/s10847-004-7455-1

DO - 10.1007/s10847-004-7455-1

M3 - Article

AN - SCOPUS:21744437173

SN - 0923-0750

VL - 52

SP - 241

EP - 245

JO - Journal of Inclusion Phenomena and Macrocyclic Chemistry

JF - Journal of Inclusion Phenomena and Macrocyclic Chemistry

IS - 3-4

ER -

Double molecular encapsulation of tetrahydrofuran by an amphiphilic calix-[4]-arene

Abstract

Keywords

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