Double-walled pyr topology networks from a novel fluoride-bridged heptanuclear metal cluster

Kai Jie Chen; John J. Perry Iv; Hayley S. Scott; Qing Yuan Yang; Michael J. Zaworotko

doi:10.1039/c5sc01515d

Double-walled pyr topology networks from a novel fluoride-bridged heptanuclear metal cluster

Kai Jie Chen, John J. Perry Iv, Hayley S. Scott, Qing Yuan Yang, Michael J. Zaworotko

Department of Chemical Sciences

University of Limerick

Research output: Contribution to journal › Article › peer-review

Abstract

Two isostructural metal-organic materials, Tripp-1-M (Tripp = 2,4,6-tris(4-pyridyl)pyridine; M = Co, Ni), that exhibit binodal 3,6-connected pyr network topology have been prepared and characterized. Tripp-1-M are based upon a novel M₇F₁₂²⁺ cluster that possesses 12 connection points but, because of double cross-linking by 3-connected Tripp ligands, it functions as a 6-connected supermolecular building block (SBB).

Original language	English
Pages (from-to)	4784-4789
Number of pages	6
Journal	Chemical Science
Volume	6
Issue number	8
DOIs	https://doi.org/10.1039/c5sc01515d
Publication status	Published - 1 Aug 2015

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title = "Double-walled pyr topology networks from a novel fluoride-bridged heptanuclear metal cluster",

abstract = "Two isostructural metal-organic materials, Tripp-1-M (Tripp = 2,4,6-tris(4-pyridyl)pyridine; M = Co, Ni), that exhibit binodal 3,6-connected pyr network topology have been prepared and characterized. Tripp-1-M are based upon a novel M7F122+ cluster that possesses 12 connection points but, because of double cross-linking by 3-connected Tripp ligands, it functions as a 6-connected supermolecular building block (SBB).",

author = "Chen, {Kai Jie} and {Perry Iv}, {John J.} and Scott, {Hayley S.} and Yang, {Qing Yuan} and Zaworotko, {Michael J.}",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry.",

year = "2015",

month = aug,

day = "1",

doi = "10.1039/c5sc01515d",

language = "English",

volume = "6",

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journal = "Chemical Science",

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T1 - Double-walled pyr topology networks from a novel fluoride-bridged heptanuclear metal cluster

AU - Chen, Kai Jie

AU - Perry Iv, John J.

AU - Scott, Hayley S.

AU - Yang, Qing Yuan

AU - Zaworotko, Michael J.

PY - 2015/8/1

Y1 - 2015/8/1

N2 - Two isostructural metal-organic materials, Tripp-1-M (Tripp = 2,4,6-tris(4-pyridyl)pyridine; M = Co, Ni), that exhibit binodal 3,6-connected pyr network topology have been prepared and characterized. Tripp-1-M are based upon a novel M7F122+ cluster that possesses 12 connection points but, because of double cross-linking by 3-connected Tripp ligands, it functions as a 6-connected supermolecular building block (SBB).

AB - Two isostructural metal-organic materials, Tripp-1-M (Tripp = 2,4,6-tris(4-pyridyl)pyridine; M = Co, Ni), that exhibit binodal 3,6-connected pyr network topology have been prepared and characterized. Tripp-1-M are based upon a novel M7F122+ cluster that possesses 12 connection points but, because of double cross-linking by 3-connected Tripp ligands, it functions as a 6-connected supermolecular building block (SBB).

UR - http://www.scopus.com/inward/record.url?scp=84937404425&partnerID=8YFLogxK

U2 - 10.1039/c5sc01515d

DO - 10.1039/c5sc01515d

M3 - Article

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VL - 6

SP - 4784

EP - 4789

JO - Chemical Science

JF - Chemical Science

IS - 8

ER -

Double-walled pyr topology networks from a novel fluoride-bridged heptanuclear metal cluster

Abstract

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