Enhanced CO2 binding affinity of a high-uptake rht-type metal-organic framework decorated with acylamide groups

Baishu Zheng; Junfeng Bai; Jingui Duan; Lukasz Wojtas; Michael J. Zaworotko

doi:10.1021/ja110042b

Enhanced CO₂ binding affinity of a high-uptake rht-type metal-organic framework decorated with acylamide groups

Baishu Zheng, Junfeng Bai, Jingui Duan, Lukasz Wojtas, Michael J. Zaworotko

Research output: Contribution to journal › Article › peer-review

Abstract

An rht-type metal-organic framework (MOF) prepared from M ₂(carboxylate)₄ (M = Cu, Co) paddlewheel clusters and a flexible C₃-symmetric hexacarboxylate ligand with acylamide groups exhibits larger CO₂ uptake, an enhanced heat of adsorption, and higher selectivity toward CO₂/N₂ in comparison with what was previously observed for an analogous MOF with alkyne groups.

Original language	English
Pages (from-to)	748-751
Number of pages	4
Journal	Journal of the American Chemical Society
Volume	133
Issue number	4
DOIs	https://doi.org/10.1021/ja110042b
Publication status	Published - 2 Feb 2011
Externally published	Yes

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10.1021/ja110042b

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title = "Enhanced CO2 binding affinity of a high-uptake rht-type metal-organic framework decorated with acylamide groups",

abstract = "An rht-type metal-organic framework (MOF) prepared from M 2(carboxylate)4 (M = Cu, Co) paddlewheel clusters and a flexible C3-symmetric hexacarboxylate ligand with acylamide groups exhibits larger CO2 uptake, an enhanced heat of adsorption, and higher selectivity toward CO2/N2 in comparison with what was previously observed for an analogous MOF with alkyne groups.",

author = "Baishu Zheng and Junfeng Bai and Jingui Duan and Lukasz Wojtas and Zaworotko, \{Michael J.\}",

year = "2011",

month = feb,

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doi = "10.1021/ja110042b",

language = "English",

volume = "133",

pages = "748--751",

journal = "Journal of the American Chemical Society",

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T1 - Enhanced CO2 binding affinity of a high-uptake rht-type metal-organic framework decorated with acylamide groups

AU - Zheng, Baishu

AU - Bai, Junfeng

AU - Duan, Jingui

AU - Wojtas, Lukasz

AU - Zaworotko, Michael J.

PY - 2011/2/2

Y1 - 2011/2/2

N2 - An rht-type metal-organic framework (MOF) prepared from M 2(carboxylate)4 (M = Cu, Co) paddlewheel clusters and a flexible C3-symmetric hexacarboxylate ligand with acylamide groups exhibits larger CO2 uptake, an enhanced heat of adsorption, and higher selectivity toward CO2/N2 in comparison with what was previously observed for an analogous MOF with alkyne groups.

AB - An rht-type metal-organic framework (MOF) prepared from M 2(carboxylate)4 (M = Cu, Co) paddlewheel clusters and a flexible C3-symmetric hexacarboxylate ligand with acylamide groups exhibits larger CO2 uptake, an enhanced heat of adsorption, and higher selectivity toward CO2/N2 in comparison with what was previously observed for an analogous MOF with alkyne groups.

UR - https://www.scopus.com/pages/publications/79851472823

U2 - 10.1021/ja110042b

DO - 10.1021/ja110042b

M3 - Article

AN - SCOPUS:79851472823

SN - 0002-7863

VL - 133

SP - 748

EP - 751

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 4

ER -

Enhanced CO₂ binding affinity of a high-uptake rht-type metal-organic framework decorated with acylamide groups

Abstract

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