Enhancement of co2 selectivity in a pillared pcu mom platform through pillar substitution

Patrick Nugent, Vanessah Rhodus, Tony Pham, Brant Tudor, Katherine Forrest, Lukasz Wojtas, Brian Space, Michael Zaworotko

Research output: Contribution to journalArticlepeer-review

Abstract

Pillar substitution in a long-known metal–organic material with saturated metal centres, [Cu(bipy)2(SiF6)]n, has afforded the first crystallographically characterized porous materials based upon TiF62− and SnF62− anions as pillars. Gas adsorption studies revealed similar surface areas and adsorption isotherms but enhanced selectivity towards CO2 vs. CH4 and N2.

Original languageEnglish
Pages (from-to)1606-1608
Number of pages3
JournalChemical Communications
Volume49
Issue number16
DOIs
Publication statusPublished - 29 Jan 2013
Externally publishedYes

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