Abstract
Pillar substitution in a long-known metal–organic material with saturated metal centres, [Cu(bipy)2(SiF6)]n, has afforded the first crystallographically characterized porous materials based upon TiF62− and SnF62− anions as pillars. Gas adsorption studies revealed similar surface areas and adsorption isotherms but enhanced selectivity towards CO2 vs. CH4 and N2.
Original language | English |
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Pages (from-to) | 1606-1608 |
Number of pages | 3 |
Journal | Chemical Communications |
Volume | 49 |
Issue number | 16 |
DOIs | |
Publication status | Published - 29 Jan 2013 |
Externally published | Yes |