Enhancement of co2 selectivity in a pillared pcu mom platform through pillar substitution

Patrick Nugent; Vanessah Rhodus; Tony Pham; Brant Tudor; Katherine Forrest; Lukasz Wojtas; Brian Space; Michael Zaworotko

doi:10.1039/c3cc37695h

Enhancement of co₂ selectivity in a pillared pcu mom platform through pillar substitution

Patrick Nugent
, Vanessah Rhodus
, Tony Pham
, Brant Tudor
, Katherine Forrest
, Lukasz Wojtas
, Brian Space
, Michael Zaworotko

University of South Florida

Research output: Contribution to journal › Article › peer-review

Abstract

Pillar substitution in a long-known metal–organic material with saturated metal centres, [Cu(bipy)₂(SiF₆)]_n, has afforded the first crystallographically characterized porous materials based upon TiF₆²⁻ and SnF₆²⁻ anions as pillars. Gas adsorption studies revealed similar surface areas and adsorption isotherms but enhanced selectivity towards CO₂ vs. CH₄ and N₂.

Original language	English
Pages (from-to)	1606-1608
Number of pages	3
Journal	Chemical Communications
Volume	49
Issue number	16
DOIs	https://doi.org/10.1039/c3cc37695h
Publication status	Published - 29 Jan 2013
Externally published	Yes

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10.1039/c3cc37695h

Cite this

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title = "Enhancement of co2 selectivity in a pillared pcu mom platform through pillar substitution",

abstract = "Pillar substitution in a long-known metal–organic material with saturated metal centres, [Cu(bipy)2(SiF6)]n, has afforded the first crystallographically characterized porous materials based upon TiF62− and SnF62− anions as pillars. Gas adsorption studies revealed similar surface areas and adsorption isotherms but enhanced selectivity towards CO2 vs. CH4 and N2.",

author = "Patrick Nugent and Vanessah Rhodus and Tony Pham and Brant Tudor and Katherine Forrest and Lukasz Wojtas and Brian Space and Michael Zaworotko",

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T1 - Enhancement of co2 selectivity in a pillared pcu mom platform through pillar substitution

AU - Nugent, Patrick

AU - Rhodus, Vanessah

AU - Pham, Tony

AU - Tudor, Brant

AU - Forrest, Katherine

AU - Wojtas, Lukasz

AU - Space, Brian

AU - Zaworotko, Michael

PY - 2013/1/29

Y1 - 2013/1/29

N2 - Pillar substitution in a long-known metal–organic material with saturated metal centres, [Cu(bipy)2(SiF6)]n, has afforded the first crystallographically characterized porous materials based upon TiF62− and SnF62− anions as pillars. Gas adsorption studies revealed similar surface areas and adsorption isotherms but enhanced selectivity towards CO2 vs. CH4 and N2.

AB - Pillar substitution in a long-known metal–organic material with saturated metal centres, [Cu(bipy)2(SiF6)]n, has afforded the first crystallographically characterized porous materials based upon TiF62− and SnF62− anions as pillars. Gas adsorption studies revealed similar surface areas and adsorption isotherms but enhanced selectivity towards CO2 vs. CH4 and N2.

UR - https://www.scopus.com/pages/publications/84873281504

U2 - 10.1039/c3cc37695h

DO - 10.1039/c3cc37695h

M3 - Article

C2 - 23340547

AN - SCOPUS:84873281504

SN - 1359-7345

VL - 49

SP - 1606

EP - 1608

JO - Chemical Communications

JF - Chemical Communications

IS - 16

ER -

Enhancement of co₂ selectivity in a pillared pcu mom platform through pillar substitution

Abstract

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