Exploitation of Guest Accessible Aliphatic Amine Functionality of a Metal-Organic Framework for Selective Detection of 2,4,6-Trinitrophenol (TNP) in Water

Soumya Mukherjee; Aamod V. Desai; Biplab Manna; Arif I. Inamdar; Sujit K. Ghosh

doi:10.1021/acs.cgd.5b00902

Exploitation of Guest Accessible Aliphatic Amine Functionality of a Metal-Organic Framework for Selective Detection of 2,4,6-Trinitrophenol (TNP) in Water

Soumya Mukherjee
, Aamod V. Desai
, Biplab Manna
, Arif I. Inamdar
, Sujit K. Ghosh

Indian Institute of Science Education and Research Pune

Research output: Contribution to journal › Article › peer-review

Abstract

Highly selective and sensitive aqueous phase-detection of the well-known nitro explosive environmental pollutant 2,4,6-trinitrophenol (TNP) by a water-stable, porous luminescent metal-organic framework has been reported. The presence of a guest accessible aliphatic amine functionality in the MOF channels has been strategically harnessed for serving the purpose of exclusive TNP-sensing in water even in concurrent presence of other nitro aromatic and nitro aliphatic analytes. (Chemical Equation Presented).

Original language	English
Pages (from-to)	4627-4634
Number of pages	8
Journal	Crystal Growth and Design
Volume	15
Issue number	9
DOIs	https://doi.org/10.1021/acs.cgd.5b00902
Publication status	Published - 2 Sep 2015
Externally published	Yes

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title = "Exploitation of Guest Accessible Aliphatic Amine Functionality of a Metal-Organic Framework for Selective Detection of 2,4,6-Trinitrophenol (TNP) in Water",

abstract = "Highly selective and sensitive aqueous phase-detection of the well-known nitro explosive environmental pollutant 2,4,6-trinitrophenol (TNP) by a water-stable, porous luminescent metal-organic framework has been reported. The presence of a guest accessible aliphatic amine functionality in the MOF channels has been strategically harnessed for serving the purpose of exclusive TNP-sensing in water even in concurrent presence of other nitro aromatic and nitro aliphatic analytes. (Chemical Equation Presented).",

author = "Soumya Mukherjee and Desai, \{Aamod V.\} and Biplab Manna and Inamdar, \{Arif I.\} and Ghosh, \{Sujit K.\}",

note = "Publisher Copyright: {\textcopyright} 2015 American Chemical Society.",

year = "2015",

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doi = "10.1021/acs.cgd.5b00902",

language = "English",

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T1 - Exploitation of Guest Accessible Aliphatic Amine Functionality of a Metal-Organic Framework for Selective Detection of 2,4,6-Trinitrophenol (TNP) in Water

AU - Mukherjee, Soumya

AU - Desai, Aamod V.

AU - Manna, Biplab

AU - Inamdar, Arif I.

AU - Ghosh, Sujit K.

PY - 2015/9/2

Y1 - 2015/9/2

N2 - Highly selective and sensitive aqueous phase-detection of the well-known nitro explosive environmental pollutant 2,4,6-trinitrophenol (TNP) by a water-stable, porous luminescent metal-organic framework has been reported. The presence of a guest accessible aliphatic amine functionality in the MOF channels has been strategically harnessed for serving the purpose of exclusive TNP-sensing in water even in concurrent presence of other nitro aromatic and nitro aliphatic analytes. (Chemical Equation Presented).

AB - Highly selective and sensitive aqueous phase-detection of the well-known nitro explosive environmental pollutant 2,4,6-trinitrophenol (TNP) by a water-stable, porous luminescent metal-organic framework has been reported. The presence of a guest accessible aliphatic amine functionality in the MOF channels has been strategically harnessed for serving the purpose of exclusive TNP-sensing in water even in concurrent presence of other nitro aromatic and nitro aliphatic analytes. (Chemical Equation Presented).

UR - https://www.scopus.com/pages/publications/84941005395

U2 - 10.1021/acs.cgd.5b00902

DO - 10.1021/acs.cgd.5b00902

M3 - Article

AN - SCOPUS:84941005395

SN - 1528-7483

VL - 15

SP - 4627

EP - 4634

JO - Crystal Growth and Design

JF - Crystal Growth and Design

IS - 9

ER -

Exploitation of Guest Accessible Aliphatic Amine Functionality of a Metal-Organic Framework for Selective Detection of 2,4,6-Trinitrophenol (TNP) in Water

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