Guest-Responsive Function of a Dynamic Metal-Organic Framework with a π Lewis Acidic Pore Surface

Biplab Joarder; Soumya Mukherjee; Abhijeet K. Chaudhari; Aamod V. Desai; Biplab Manna; Sujit K. Ghosh

doi:10.1002/chem.201402855

Guest-Responsive Function of a Dynamic Metal-Organic Framework with a π Lewis Acidic Pore Surface

Biplab Joarder, Soumya Mukherjee, Abhijeet K. Chaudhari, Aamod V. Desai, Biplab Manna, Sujit K. Ghosh

Indian Institute of Science Education and Research Pune

Research output: Contribution to journal › Article › peer-review

Abstract

A 3D dynamic coordination framework with an electron-deficient pore surface has been synthesized by using Zn^II (having a variable coordination number) and a predesigned flexible π-electron-deficient core-based ligand, exhibiting chemical separations based on pore surface functionalization (π Lewis acidic pore surfaces and open metal sites) and framework flexibility, giving rise to a unique smart guest-responsive material.

Original language	English
Pages (from-to)	15303-15308
Number of pages	6
Journal	Chemistry - A European Journal
Volume	20
Issue number	47
DOIs	https://doi.org/10.1002/chem.201402855
Publication status	Published - 1 Nov 2014
Externally published	Yes

Keywords

coordination polymers
dynamic frameworks
host-guest systems
separation
sorption

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abstract = "A 3D dynamic coordination framework with an electron-deficient pore surface has been synthesized by using ZnII (having a variable coordination number) and a predesigned flexible π-electron-deficient core-based ligand, exhibiting chemical separations based on pore surface functionalization (π Lewis acidic pore surfaces and open metal sites) and framework flexibility, giving rise to a unique smart guest-responsive material.",

keywords = "coordination polymers, dynamic frameworks, host-guest systems, separation, sorption",

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AU - Desai, Aamod V.

AU - Manna, Biplab

AU - Ghosh, Sujit K.

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AB - A 3D dynamic coordination framework with an electron-deficient pore surface has been synthesized by using ZnII (having a variable coordination number) and a predesigned flexible π-electron-deficient core-based ligand, exhibiting chemical separations based on pore surface functionalization (π Lewis acidic pore surfaces and open metal sites) and framework flexibility, giving rise to a unique smart guest-responsive material.

KW - coordination polymers

KW - dynamic frameworks

KW - host-guest systems

KW - separation

KW - sorption

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Guest-Responsive Function of a Dynamic Metal-Organic Framework with a π Lewis Acidic Pore Surface

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Keywords

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