TY - JOUR
T1 - Hard wear-resistant TiAlSiCN/MoSeC coatings with a low friction coefficient at room and elevated temperatures
AU - Bondarev, A. V.
AU - Kiryukhantsev-Korneev, Ph V.
AU - Shtansky, D. V.
N1 - Publisher Copyright:
© 2015, Allerton Press, Inc.
PY - 2015
Y1 - 2015
N2 - TiAlSiCN and TiAlSiCN/MoSeC coatings are fabricated by magnetron sputtering of segmented SHS and compacted powder targets. The structure and composition of coatings are investigated by X-ray phase analysis, X-ray photoelectron spectroscopy, Raman spectroscopy, transmission electron microscopy, and glow-discharge optical emission spectroscopy. The TiAlSiCN coating is based on the fcc phase with crystallite size <15 nm; the crystallite size decreases under sputtering of TiAlSiCN and MoSeC segments in a ratio of 3: 1 and crystallites amorphized at a ratio of 2: 2. The MoSe2 phase is also found in TiAlSiCN/MoSeC coatings. According to the results of nanoindentation, the hardness of TiAlSiCN coatings is 40 GPa and that of TiAlSiCN/MoSeC coatings is 28 and 12 GPa at ratios of 3: 1 and 2: 2, respectively. The friction coefficient of TiAlSiCN coatings at room temperature is 0.75, it decreases to 0.05 after the introduction of MoSeC, and wear resistance of coatings increases as well. A low friction coefficient (<0.1) under tribological tests of TiAl-SiCN/MoSeC coatings with continuous heating is invariable up to 300°C.
AB - TiAlSiCN and TiAlSiCN/MoSeC coatings are fabricated by magnetron sputtering of segmented SHS and compacted powder targets. The structure and composition of coatings are investigated by X-ray phase analysis, X-ray photoelectron spectroscopy, Raman spectroscopy, transmission electron microscopy, and glow-discharge optical emission spectroscopy. The TiAlSiCN coating is based on the fcc phase with crystallite size <15 nm; the crystallite size decreases under sputtering of TiAlSiCN and MoSeC segments in a ratio of 3: 1 and crystallites amorphized at a ratio of 2: 2. The MoSe2 phase is also found in TiAlSiCN/MoSeC coatings. According to the results of nanoindentation, the hardness of TiAlSiCN coatings is 40 GPa and that of TiAlSiCN/MoSeC coatings is 28 and 12 GPa at ratios of 3: 1 and 2: 2, respectively. The friction coefficient of TiAlSiCN coatings at room temperature is 0.75, it decreases to 0.05 after the introduction of MoSeC, and wear resistance of coatings increases as well. A low friction coefficient (<0.1) under tribological tests of TiAl-SiCN/MoSeC coatings with continuous heating is invariable up to 300°C.
KW - antifriction nanostructured coatings
KW - high hardness
KW - high-temperature tribology
KW - magnetron sputtering
UR - http://www.scopus.com/inward/record.url?scp=84924958785&partnerID=8YFLogxK
U2 - 10.3103/S106782121501006X
DO - 10.3103/S106782121501006X
M3 - Article
AN - SCOPUS:84924958785
SN - 1067-8212
VL - 56
SP - 107
EP - 113
JO - Russian Journal of Non-Ferrous Metals
JF - Russian Journal of Non-Ferrous Metals
IS - 1
ER -