Harnessing Lewis acidic open metal sites of metal-organic frameworks: The foremost route to achieve highly selective benzene sorption over cyclohexane

Soumya Mukherjee; Biplab Manna; Aamod V. Desai; Yuefeng Yin; Rajamani Krishna; Ravichandar Babarao; Sujit K. Ghosh

doi:10.1039/c6cc03015g

Harnessing Lewis acidic open metal sites of metal-organic frameworks: The foremost route to achieve highly selective benzene sorption over cyclohexane

Soumya Mukherjee
, Biplab Manna
, Aamod V. Desai
, Yuefeng Yin
, Rajamani Krishna
, Ravichandar Babarao
, Sujit K. Ghosh

Research output: Contribution to journal › Article › peer-review

Abstract

π-Complexation triggered Lewis acid-base interactions between open metal sites (OMS) of metal-organic frameworks (MOFs), and π-e^- rich adsorptive benzene (Bz) is exploited to establish M-MOF-74 as the best Bz-selective MOF sorbent, marking the first report of utilizing OMS behind benzene/cyclohexane separation; a key advance from the energy-economy standpoint of industrial separation.

Original language	English
Pages (from-to)	8215-8218
Number of pages	4
Journal	Chemical Communications
Volume	52
Issue number	53
DOIs	https://doi.org/10.1039/c6cc03015g
Publication status	Published - 2016
Externally published	Yes

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title = "Harnessing Lewis acidic open metal sites of metal-organic frameworks: The foremost route to achieve highly selective benzene sorption over cyclohexane",

abstract = "π-Complexation triggered Lewis acid-base interactions between open metal sites (OMS) of metal-organic frameworks (MOFs), and π-e- rich adsorptive benzene (Bz) is exploited to establish M-MOF-74 as the best Bz-selective MOF sorbent, marking the first report of utilizing OMS behind benzene/cyclohexane separation; a key advance from the energy-economy standpoint of industrial separation.",

author = "Soumya Mukherjee and Biplab Manna and Desai, \{Aamod V.\} and Yuefeng Yin and Rajamani Krishna and Ravichandar Babarao and Ghosh, \{Sujit K.\}",

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year = "2016",

doi = "10.1039/c6cc03015g",

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T2 - The foremost route to achieve highly selective benzene sorption over cyclohexane

AU - Mukherjee, Soumya

AU - Manna, Biplab

AU - Desai, Aamod V.

AU - Yin, Yuefeng

AU - Krishna, Rajamani

AU - Babarao, Ravichandar

AU - Ghosh, Sujit K.

N1 - Publisher Copyright: © The Royal Society of Chemistry 2016.

PY - 2016

Y1 - 2016

N2 - π-Complexation triggered Lewis acid-base interactions between open metal sites (OMS) of metal-organic frameworks (MOFs), and π-e- rich adsorptive benzene (Bz) is exploited to establish M-MOF-74 as the best Bz-selective MOF sorbent, marking the first report of utilizing OMS behind benzene/cyclohexane separation; a key advance from the energy-economy standpoint of industrial separation.

AB - π-Complexation triggered Lewis acid-base interactions between open metal sites (OMS) of metal-organic frameworks (MOFs), and π-e- rich adsorptive benzene (Bz) is exploited to establish M-MOF-74 as the best Bz-selective MOF sorbent, marking the first report of utilizing OMS behind benzene/cyclohexane separation; a key advance from the energy-economy standpoint of industrial separation.

UR - https://www.scopus.com/pages/publications/84975853519

U2 - 10.1039/c6cc03015g

DO - 10.1039/c6cc03015g

M3 - Article

AN - SCOPUS:84975853519

SN - 1359-7345

VL - 52

SP - 8215

EP - 8218

JO - Chemical Communications

JF - Chemical Communications

IS - 53

ER -

Harnessing Lewis acidic open metal sites of metal-organic frameworks: The foremost route to achieve highly selective benzene sorption over cyclohexane

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