Helical coordination polymers with large chiral cavities

Kumar Biradha; Corey Seward; Michael J. Zaworotko

doi:10.1002/(sici)1521-3773(19990215)38:4<492::aid-anie492>3.0.co;2-%23

Helical coordination polymers with large chiral cavities

Kumar Biradha
, Corey Seward
, Michael J. Zaworotko

University of Winnipeg

Research output: Contribution to journal › Article › peer-review

Abstract

A quarter of the unit cell volume of [{Ni(4,4'-dipy)(3- nitrobenzoate)₂(MeOH)₂}(n)], which crystallizes in the form of helices, is occupied by large chiral cavities (400-500 Å³). The cavities are capable of encapsulating not only single molecules, but also face-to-face dimers of nitrobenzene (see stick model). 4,4'-dipy = 4,4'-bipyridine.

Original language	English
Pages (from-to)	492-495
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	38
Issue number	4
DOIs	https://doi.org/10.1002/(sici)1521-3773(19990215)38:4<492::aid-anie492>3.0.co;2-%23
Publication status	Published - 15 Feb 1999
Externally published	Yes

Keywords

Chirality
Coordination polymers
Crystal engineering
Helical structures
Supramolecular chemistry

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10.1002/(sici)1521-3773(19990215)38:4<492::aid-anie492>3.0.co;2-%23

Cite this

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title = "Helical coordination polymers with large chiral cavities",

abstract = "A quarter of the unit cell volume of [\{Ni(4,4'-dipy)(3- nitrobenzoate)2(MeOH)2\}(n)], which crystallizes in the form of helices, is occupied by large chiral cavities (400-500 {\AA}3). The cavities are capable of encapsulating not only single molecules, but also face-to-face dimers of nitrobenzene (see stick model). 4,4'-dipy = 4,4'-bipyridine.",

keywords = "Chirality, Coordination polymers, Crystal engineering, Helical structures, Supramolecular chemistry",

author = "Kumar Biradha and Corey Seward and Zaworotko, \{Michael J.\}",

year = "1999",

month = feb,

day = "15",

doi = "10.1002/(sici)1521-3773(19990215)38:4<492::aid-anie492>3.0.co;2-\%23",

language = "English",

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journal = "Angewandte Chemie - International Edition",

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TY - JOUR

T1 - Helical coordination polymers with large chiral cavities

AU - Biradha, Kumar

AU - Seward, Corey

AU - Zaworotko, Michael J.

PY - 1999/2/15

Y1 - 1999/2/15

N2 - A quarter of the unit cell volume of [{Ni(4,4'-dipy)(3- nitrobenzoate)2(MeOH)2}(n)], which crystallizes in the form of helices, is occupied by large chiral cavities (400-500 Å3). The cavities are capable of encapsulating not only single molecules, but also face-to-face dimers of nitrobenzene (see stick model). 4,4'-dipy = 4,4'-bipyridine.

AB - A quarter of the unit cell volume of [{Ni(4,4'-dipy)(3- nitrobenzoate)2(MeOH)2}(n)], which crystallizes in the form of helices, is occupied by large chiral cavities (400-500 Å3). The cavities are capable of encapsulating not only single molecules, but also face-to-face dimers of nitrobenzene (see stick model). 4,4'-dipy = 4,4'-bipyridine.

KW - Chirality

KW - Coordination polymers

KW - Crystal engineering

KW - Helical structures

KW - Supramolecular chemistry

UR - https://www.scopus.com/pages/publications/0033558167

U2 - 10.1002/(sici)1521-3773(19990215)38:4<492::aid-anie492>3.0.co;2-%23

DO - 10.1002/(sici)1521-3773(19990215)38:4<492::aid-anie492>3.0.co;2-%23

M3 - Article

AN - SCOPUS:0033558167

SN - 1433-7851

VL - 38

SP - 492

EP - 495

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 4

ER -

Helical coordination polymers with large chiral cavities

Abstract

Keywords

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