Hemilabile Binding of Acetylene in an Amide-Rich Ultramicroporous MOF Enables Strong Acetylene Selectivity

Subhajit Dutta; Soumya Mukherjee; Sousa Javan Nikkhah; Omid T. Qazvini; Gourab K. Dam; Matthias Vandichel; Tarak Nath Mandal; Sujit K. Ghosh

doi:10.1021/acs.inorgchem.4c01933

Hemilabile Binding of Acetylene in an Amide-Rich Ultramicroporous MOF Enables Strong Acetylene Selectivity

Subhajit Dutta
, Soumya Mukherjee
, Sousa Javan Nikkhah
, Omid T. Qazvini
, Gourab K. Dam
, Matthias Vandichel
, Tarak Nath Mandal
, Sujit K. Ghosh

Research output: Contribution to journal › Article › peer-review

Abstract

Thanks to a hemilabile amide-based binding site, a previously unreported amide-functionalized metal-organic framework (MOF) exhibits high acetylene affinity over ethylene, methane, and carbon dioxide, three-in-one.

Original language	English
Pages (from-to)	12404-12408
Number of pages	5
Journal	Inorganic Chemistry
Volume	63
Issue number	27
DOIs	https://doi.org/10.1021/acs.inorgchem.4c01933
Publication status	Published - 8 Jul 2024

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10.1021/acs.inorgchem.4c01933

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title = "Hemilabile Binding of Acetylene in an Amide-Rich Ultramicroporous MOF Enables Strong Acetylene Selectivity",

abstract = "Thanks to a hemilabile amide-based binding site, a previously unreported amide-functionalized metal-organic framework (MOF) exhibits high acetylene affinity over ethylene, methane, and carbon dioxide, three-in-one.",

author = "Subhajit Dutta and Soumya Mukherjee and \{Javan Nikkhah\}, Sousa and Qazvini, \{Omid T.\} and Dam, \{Gourab K.\} and Matthias Vandichel and Mandal, \{Tarak Nath\} and Ghosh, \{Sujit K.\}",

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doi = "10.1021/acs.inorgchem.4c01933",

language = "English",

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journal = "Inorganic Chemistry",

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T1 - Hemilabile Binding of Acetylene in an Amide-Rich Ultramicroporous MOF Enables Strong Acetylene Selectivity

AU - Dutta, Subhajit

AU - Mukherjee, Soumya

AU - Javan Nikkhah, Sousa

AU - Qazvini, Omid T.

AU - Dam, Gourab K.

AU - Vandichel, Matthias

AU - Mandal, Tarak Nath

AU - Ghosh, Sujit K.

PY - 2024/7/8

Y1 - 2024/7/8

N2 - Thanks to a hemilabile amide-based binding site, a previously unreported amide-functionalized metal-organic framework (MOF) exhibits high acetylene affinity over ethylene, methane, and carbon dioxide, three-in-one.

AB - Thanks to a hemilabile amide-based binding site, a previously unreported amide-functionalized metal-organic framework (MOF) exhibits high acetylene affinity over ethylene, methane, and carbon dioxide, three-in-one.

UR - https://www.scopus.com/pages/publications/85196769449

U2 - 10.1021/acs.inorgchem.4c01933

DO - 10.1021/acs.inorgchem.4c01933

M3 - Article

C2 - 38913858

AN - SCOPUS:85196769449

SN - 0020-1669

VL - 63

SP - 12404

EP - 12408

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 27

ER -

Hemilabile Binding of Acetylene in an Amide-Rich Ultramicroporous MOF Enables Strong Acetylene Selectivity

Abstract

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