High-nuclearity manganese carbonyl complexes: Structures of [{Mn(μ3-OH)(CO)3}4] and [Mn 73-OH)8(CO)18]

Michael D. Clerk, Michael J. Zaworotko

Research output: Contribution to journalArticlepeer-review

Abstract

One-pot high-yield synthesis of the cubane-like complexes [{Mn(μ3-OH)(CO)3}4] 1, and mixed-valence [Mn73-OH)8(CO)18 2, is reported: 1 and 2 have been characterized via X-ray crystallography, 2 being the largest Mn carbonyl complex yet structurally characterized.

Original languageEnglish
Pages (from-to)1607-1608
Number of pages2
JournalJournal of the Chemical Society, Chemical Communications
Issue number22
DOIs
Publication statusPublished - 1991
Externally publishedYes

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