High-nuclearity manganese carbonyl complexes: Structures of [{Mn(μ3-OH)(CO)3}4] and [Mn 7(μ3-OH)8(CO)18]

Michael D. Clerk; Michael J. Zaworotko

doi:10.1039/C39910001607

High-nuclearity manganese carbonyl complexes: Structures of [{Mn(μ₃-OH)(CO)₃}₄] and [Mn ₇(μ₃-OH)₈(CO)₁₈]

Michael D. Clerk
, Michael J. Zaworotko

Dalhousie University
Saint Mary's University Halifax

Research output: Contribution to journal › Article › peer-review

Abstract

One-pot high-yield synthesis of the cubane-like complexes [{Mn(μ₃-OH)(CO)₃}₄] 1, and mixed-valence [Mn₇(μ₃-OH)₈(CO)₁₈ 2, is reported: 1 and 2 have been characterized via X-ray crystallography, 2 being the largest Mn carbonyl complex yet structurally characterized.

Original language	English
Pages (from-to)	1607-1608
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	22
DOIs	https://doi.org/10.1039/C39910001607
Publication status	Published - 1991
Externally published	Yes

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title = "High-nuclearity manganese carbonyl complexes: Structures of [\{Mn(μ3-OH)(CO)3\}4] and [Mn 7(μ3-OH)8(CO)18]",

abstract = "One-pot high-yield synthesis of the cubane-like complexes [\{Mn(μ3-OH)(CO)3\}4] 1, and mixed-valence [Mn7(μ3-OH)8(CO)18 2, is reported: 1 and 2 have been characterized via X-ray crystallography, 2 being the largest Mn carbonyl complex yet structurally characterized.",

author = "Clerk, \{Michael D.\} and Zaworotko, \{Michael J.\}",

year = "1991",

doi = "10.1039/C39910001607",

language = "English",

pages = "1607--1608",

journal = "Journal of the Chemical Society, Chemical Communications",

issn = "0022-4936",

number = "22",

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TY - JOUR

T1 - High-nuclearity manganese carbonyl complexes

T2 - Structures of [{Mn(μ3-OH)(CO)3}4] and [Mn 7(μ3-OH)8(CO)18]

AU - Clerk, Michael D.

AU - Zaworotko, Michael J.

PY - 1991

Y1 - 1991

N2 - One-pot high-yield synthesis of the cubane-like complexes [{Mn(μ3-OH)(CO)3}4] 1, and mixed-valence [Mn7(μ3-OH)8(CO)18 2, is reported: 1 and 2 have been characterized via X-ray crystallography, 2 being the largest Mn carbonyl complex yet structurally characterized.

AB - One-pot high-yield synthesis of the cubane-like complexes [{Mn(μ3-OH)(CO)3}4] 1, and mixed-valence [Mn7(μ3-OH)8(CO)18 2, is reported: 1 and 2 have been characterized via X-ray crystallography, 2 being the largest Mn carbonyl complex yet structurally characterized.

UR - https://www.scopus.com/pages/publications/37049074640

U2 - 10.1039/C39910001607

DO - 10.1039/C39910001607

M3 - Article

AN - SCOPUS:37049074640

SN - 0022-4936

SP - 1607

EP - 1608

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 22

ER -

High-nuclearity manganese carbonyl complexes: Structures of [{Mn(μ₃-OH)(CO)₃}₄] and [Mn ₇(μ₃-OH)₈(CO)₁₈]

Abstract

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